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dc.contributor.authorLiu, Yanpin
dc.contributor.authorChen, Chaohuang
dc.contributor.authorLi, Huaifeng
dc.contributor.authorHuang, Kuo-Wei
dc.contributor.authorTan, Jianwei
dc.contributor.authorWeng, Zhiqiang
dc.date.accessioned2015-08-03T11:35:22Z
dc.date.available2015-08-03T11:35:22Z
dc.date.issued2013-10-18
dc.identifier.citationLiu, Y., Chen, C., Li, H., Huang, K.-W., Tan, J., & Weng, Z. (2013). Efficient SN2 Fluorination of Primary and Secondary Alkyl Bromides by Copper(I) Fluoride Complexes. Organometallics, 32(21), 6587–6592. doi:10.1021/om4008967
dc.identifier.issn02767333
dc.identifier.doi10.1021/om4008967
dc.identifier.urihttp://hdl.handle.net/10754/563082
dc.description.abstractCopper(I) fluoride complexes ligated by phenanthroline derivatives have been synthesized and structurally characterized by X-ray crystallography. These complexes adopt as either ionic or neutral forms in the solid state, depending on the steric bulkiness of the substituent groups on the phenanthroline ligands. These complexes react with primary and secondary alkyl bromides to produce the corresponding alkyl fluorides in modest to good yields. This new method is compatible with a variety of important functional groups such as ether, thioether, amide, nitrile, methoxyl, hydroxyl, ketone, ester, and heterocycle moieties. © 2013 American Chemical Society.
dc.description.sponsorshipWe acknowledge the financial support from National Natural Science Foundation of China (21072030), Research Fund for the Doctoral Program of Higher Education of China (No. 20123514110003), SRF for ROCS, SEM (J20121707), the Science Foundation of the Fujian Province, China (2013J01040), and Fuzhou University (022318, 022494) to Z.W. and King Abdullah University of Science and Technology to K.-W.H.
dc.publisherAmerican Chemical Society (ACS)
dc.titleEfficient SN2 fluorination of primary and secondary alkyl bromides by copper(I) fluoride complexes
dc.typeArticle
dc.contributor.departmentChemical Science Program
dc.contributor.departmentHomogeneous Catalysis Laboratory (HCL)
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalOrganometallics
dc.contributor.institutionDepartment of Chemistry, Fuzhou University, Fujian 350108, China
kaust.personLi, Huaifeng
kaust.personHuang, Kuo-Wei
dc.relation.issupplementedbyDOI:10.5517/cc10wc2b
dc.relation.issupplementedbyDOI:10.5517/cc10wc3c
dc.relation.issupplementedbyDOI:10.5517/cc10wc4d
display.relations<b> Is Supplemented By:</b> <br/> <ul><li><i>[Dataset]</i> <br/> Liu, Y., Chen, C., Li, H., Huang, K.-W., Tan, J., & Weng, Z. (2014). CCDC 949811: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc10wc2b. DOI: <a href="https://doi.org/10.5517/cc10wc2b">10.5517/cc10wc2b</a> HANDLE: <a href="http://hdl.handle.net/10754/624240">10754/624240</a></li><li><i>[Dataset]</i> <br/> Liu, Y., Chen, C., Li, H., Huang, K.-W., Tan, J., & Weng, Z. (2014). CCDC 949812: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc10wc3c. DOI: <a href="https://doi.org/10.5517/cc10wc3c">10.5517/cc10wc3c</a> HANDLE: <a href="http://hdl.handle.net/10754/624241">10754/624241</a></li><li><i>[Dataset]</i> <br/> Liu, Y., Chen, C., Li, H., Huang, K.-W., Tan, J., & Weng, Z. (2014). CCDC 949813: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc10wc4d. DOI: <a href="https://doi.org/10.5517/cc10wc4d">10.5517/cc10wc4d</a> HANDLE: <a href="http://hdl.handle.net/10754/624242">10754/624242</a></li></ul>
dc.date.published-online2013-10-18
dc.date.published-print2013-11-11


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