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dc.contributor.authorChen, Yin
dc.contributor.authorCallens, Emmanuel
dc.contributor.authorAbou-Hamad, Edy
dc.contributor.authorBasset, Jean-Marie
dc.date.accessioned2015-08-03T11:34:57Z
dc.date.available2015-08-03T11:34:57Z
dc.date.issued2013-11
dc.identifier.citationChen, Y., Callens, E., Abou-hamad, E., & Basset, J.-M. (2013). [(SiO)TaV(CH2)Cl2], the first tantalum methylidene species prepared and identified on the silica surface. Journal of Organometallic Chemistry, 744, 3–6. doi:10.1016/j.jorganchem.2013.04.050
dc.identifier.issn0022328X
dc.identifier.doi10.1016/j.jorganchem.2013.04.050
dc.identifier.urihttp://hdl.handle.net/10754/563064
dc.description.abstractA novel surface tantalum methylidene [(≡SiO)TaV (=CH 2)Cl2] was obtained via thermal decomposition of the well-defined surface species [(≡SiO)TaVCl2Me 2]. This first surface tantalum methylidene ever synthesized has been fully characterized and the kinetics of the a-hydrogen abstraction reaction has also been investigated in the heterogeneous system. © 2013 Elsevier B.V. All rights reserved.
dc.description.sponsorshipWe thanks KAUST for the financial support and YC gratefully acknowledges generous donation from SABIC.
dc.publisherElsevier BV
dc.subject&alpha-Hydrogen abstraction
dc.subjectKinetics
dc.subjectSurface organometallics chemistry
dc.subjectSurface tantalum methylidene
dc.title[(≡SiO)TaV (=CH2)Cl2], the first tantalum methylidene species prepared and identified on the silica surface
dc.typeArticle
dc.contributor.departmentChemical Science Program
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentKAUST Solar Center (KSC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalJournal of Organometallic Chemistry
kaust.personChen, Yin
kaust.personCallens, Emmanuel
kaust.personAbou-Hamad, Edy
kaust.personBasset, Jean-Marie


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