[(≡SiO)TaV (=CH2)Cl2], the first tantalum methylidene species prepared and identified on the silica surface
Type
ArticleKAUST Department
Chemical Science ProgramKAUST Catalysis Center (KCC)
KAUST Solar Center (KSC)
Physical Science and Engineering (PSE) Division
Date
2013-11Permanent link to this record
http://hdl.handle.net/10754/563064
Metadata
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A novel surface tantalum methylidene [(≡SiO)TaV (=CH 2)Cl2] was obtained via thermal decomposition of the well-defined surface species [(≡SiO)TaVCl2Me 2]. This first surface tantalum methylidene ever synthesized has been fully characterized and the kinetics of the a-hydrogen abstraction reaction has also been investigated in the heterogeneous system. © 2013 Elsevier B.V. All rights reserved.Citation
Chen, Y., Callens, E., Abou-hamad, E., & Basset, J.-M. (2013). [(SiO)TaV(CH2)Cl2], the first tantalum methylidene species prepared and identified on the silica surface. Journal of Organometallic Chemistry, 744, 3–6. doi:10.1016/j.jorganchem.2013.04.050Sponsors
We thanks KAUST for the financial support and YC gratefully acknowledges generous donation from SABIC.Publisher
Elsevier BVae974a485f413a2113503eed53cd6c53
10.1016/j.jorganchem.2013.04.050