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dc.contributor.authorSwaidan, Raja
dc.contributor.authorMa, Xiaohua
dc.contributor.authorLitwiller, Eric
dc.contributor.authorPinnau, Ingo
dc.date.accessioned2015-08-03T11:34:50Z
dc.date.available2015-08-03T11:34:50Z
dc.date.issued2013-11
dc.identifier.citationSwaidan, R., Ma, X., Litwiller, E., & Pinnau, I. (2013). High pressure pure- and mixed-gas separation of CO2/CH4 by thermally-rearranged and carbon molecular sieve membranes derived from a polyimide of intrinsic microporosity. Journal of Membrane Science, 447, 387–394. doi:10.1016/j.memsci.2013.07.057
dc.identifier.issn03767388
dc.identifier.doi10.1016/j.memsci.2013.07.057
dc.identifier.urihttp://hdl.handle.net/10754/563059
dc.description.abstractNatural gas sweetening, one of the most promising venues for the growth of the membrane gas separation industry, is dominated by polymeric materials with relatively low permeabilities and moderate selectivities. One strategy towards improving the gas transport properties of a polymer is enhancement of microporosity either by design of polymers of intrinsic microporosity (PIMs) or by thermal treatment of polymeric precursors. For the first time, the mixed-gas CO2/CH4 transport properties are investigated for a complete series of thermally-rearranged (TR) (440°C) and carbon molecular sieve (CMS) membranes (600, 630 and 800°C) derived from a polyimide of intrinsic microporosity (PIM-6FDA-OH). The pressure dependence of permeability and selectivity is reported up to 30bar for 1:1, CO2:CH4 mixed-gas feeds at 35°C. The TR membrane exhibited ~15% higher CO2/CH4 selectivity relative to pure-gas feeds due to reductions in mixed-gas CH4 permeability reaching 27% at 30bar. This is attributed to increased hindrance of CH4 transport by co-permeation of CO2. Interestingly, unusual increases in mixed-gas CH4 permeabilities relative to pure-gas values were observed for the CMS membranes, resulting in up to 50% losses in mixed-gas selectivity over the applied pressure range. © 2013 Elsevier B.V.
dc.description.sponsorshipThis research was supported by King Abdullah University of Science and Technology baseline funding for Ingo Pinnau.
dc.publisherElsevier BV
dc.subjectCarbon molecular sieve
dc.subjectCO2/CH4 mixed-gas permeation
dc.subjectGas separation
dc.subjectIntrinsic microporosity
dc.subjectThermal-rearrangement
dc.titleHigh pressure pure- and mixed-gas separation of CO2/CH4 by thermally-rearranged and carbon molecular sieve membranes derived from a polyimide of intrinsic microporosity
dc.typeArticle
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Center
dc.contributor.departmentChemical Engineering Program
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalJournal of Membrane Science
kaust.personSwaidan, Raja
kaust.personMa, Xiaohua
kaust.personLitwiller, Eric
kaust.personPinnau, Ingo


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