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dc.contributor.authorSchoedel, Alexander
dc.contributor.authorBoyette, Wesley
dc.contributor.authorWojtas, Łukasz
dc.contributor.authorEddaoudi, Mohamed
dc.contributor.authorZaworotko, Michael J.
dc.date.accessioned2015-08-03T11:18:00Z
dc.date.available2015-08-03T11:18:00Z
dc.date.issued2013-09-11
dc.identifier.citationSchoedel, A., Boyette, W., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2013). A Family of Porous Lonsdaleite-e Networks Obtained through Pillaring of Decorated Kagomé Lattice Sheets. Journal of the American Chemical Society, 135(38), 14016–14019. doi:10.1021/ja406030p
dc.identifier.issn00027863
dc.identifier.doi10.1021/ja406030p
dc.identifier.urihttp://hdl.handle.net/10754/562982
dc.description.abstractA new and versatile class of metal-organic materials (MOMs) with augmented lonsdaleite-e (lon-e-a) topology is presented herein. This family of lon-e nets are built by pillaring of hexagonal two-dimensional kagomé (kag) lattices constructed from well-known [Zn2(CO2R)4] paddlewheel molecular building blocks (MBBs) connected by 1,3- benzenedicarboxylate (bdc2-) linkers. The pillars are [Cr 3(μ3-O)(RCO2)]6 trigonal prismatic primary MBBs decorated by six pyridyl moieties (tp-PMBB-1). The three-fold symmetry (D3h) of tp-PMBB-1 is complementary with the alternating orientation of the axial sites of the paddlewheel MBBs and enables triple cross-linking of the kag layers by each pillar. These MOMs represent the first examples of axial-to-axial pillared undulating kag layers, and they are readily fine-tuned because the bdc2- moieties can be varied at their 5-position without changing the overall structure. This lon-e platform possesses functionalized hexagonal channels since the kag lattices are necessarily eclipsed. The effects of the substituent at the 5-positions of the bdc 2- linkers upon gas adsorption, particularly the heats of adsorption of carbon dioxide and methane, were studied. © 2013 American Chemical Society.
dc.description.sponsorshipThis work is supported by Award No. FIC/2010/06, made by the King Abdullah University of Science and Technology (KAUST). The authors thank Prof. D. M. Proserpio (Universita stegli di Milano) for assistance with topological classification.
dc.publisherAmerican Chemical Society (ACS)
dc.titleA family of porous lonsdaleite-e networks obtained through pillaring of decorated kagomé lattice sheets
dc.typeArticle
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Center
dc.contributor.departmentChemical Science Program
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalJournal of the American Chemical Society
dc.contributor.institutionDepartment of Chemistry, University of South Florida, 4202 East Fowler Avenue, CHE205, Tampa, FL 33620, United States
kaust.personEddaoudi, Mohamed
kaust.grant.numberFIC/2010/06
dc.relation.issupplementedbyDOI:10.5517/cc11k2m9
dc.relation.issupplementedbyDOI:10.5517/cc11k2nb
dc.relation.issupplementedbyDOI:10.5517/cc11k2pc
dc.relation.issupplementedbyDOI:10.5517/cc11k2qd
dc.relation.issupplementedbyDOI:10.5517/cc11k2rf
dc.relation.issupplementedbyDOI:10.5517/cc11k2sg
dc.relation.issupplementedbyDOI:10.5517/cc11k2th
dc.relation.issupplementedbyDOI:10.5517/cc11k2vj
dc.relation.issupplementedbyDOI:10.5517/cc11k2wk
display.relations<b> Is Supplemented By:</b> <br/> <ul><li><i>[Dataset]</i> <br/> Schoedel, A., Boyette, W., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 969730: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc11k2m9. DOI: <a href="https://doi.org/10.5517/cc11k2m9">10.5517/cc11k2m9</a> HANDLE: <a href="http://hdl.handle.net/10754/624273">10754/624273</a></li><li><i>[Dataset]</i> <br/> Schoedel, A., Boyette, W., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 969731: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc11k2nb. DOI: <a href="https://doi.org/10.5517/cc11k2nb">10.5517/cc11k2nb</a> HANDLE: <a href="http://hdl.handle.net/10754/624274">10754/624274</a></li><li><i>[Dataset]</i> <br/> Schoedel, A., Boyette, W., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 969732: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc11k2pc. DOI: <a href="https://doi.org/10.5517/cc11k2pc">10.5517/cc11k2pc</a> HANDLE: <a href="http://hdl.handle.net/10754/624275">10754/624275</a></li><li><i>[Dataset]</i> <br/> Schoedel, A., Boyette, W., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 969733: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc11k2qd. DOI: <a href="https://doi.org/10.5517/cc11k2qd">10.5517/cc11k2qd</a> HANDLE: <a href="http://hdl.handle.net/10754/624276">10754/624276</a></li><li><i>[Dataset]</i> <br/> Schoedel, A., Boyette, W., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 969734: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc11k2rf. DOI: <a href="https://doi.org/10.5517/cc11k2rf">10.5517/cc11k2rf</a> HANDLE: <a href="http://hdl.handle.net/10754/624277">10754/624277</a></li><li><i>[Dataset]</i> <br/> Schoedel, A., Boyette, W., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 969735: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc11k2sg. DOI: <a href="https://doi.org/10.5517/cc11k2sg">10.5517/cc11k2sg</a> HANDLE: <a href="http://hdl.handle.net/10754/624278">10754/624278</a></li><li><i>[Dataset]</i> <br/> Schoedel, A., Boyette, W., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 969736: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc11k2th. DOI: <a href="https://doi.org/10.5517/cc11k2th">10.5517/cc11k2th</a> HANDLE: <a href="http://hdl.handle.net/10754/624279">10754/624279</a></li><li><i>[Dataset]</i> <br/> Schoedel, A., Boyette, W., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 969737: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc11k2vj. DOI: <a href="https://doi.org/10.5517/cc11k2vj">10.5517/cc11k2vj</a> HANDLE: <a href="http://hdl.handle.net/10754/624280">10754/624280</a></li><li><i>[Dataset]</i> <br/> Schoedel, A., Boyette, W., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 969738: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc11k2wk. DOI: <a href="https://doi.org/10.5517/cc11k2wk">10.5517/cc11k2wk</a> HANDLE: <a href="http://hdl.handle.net/10754/624281">10754/624281</a></li></ul>
dc.date.published-online2013-09-11
dc.date.published-print2013-09-25


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