• Login
    View Item 
    •   Home
    • Research
    • Articles
    • View Item
    •   Home
    • Research
    • Articles
    • View Item
    JavaScript is disabled for your browser. Some features of this site may not work without it.

    Browse

    All of KAUSTCommunitiesIssue DateSubmit DateThis CollectionIssue DateSubmit Date

    My Account

    Login

    Quick Links

    Open Access PolicyORCID LibguidePlumX LibguideSubmit an Item

    Statistics

    Display statistics

    A family of porous lonsdaleite-e networks obtained through pillaring of decorated kagomé lattice sheets

    • CSV
    • RefMan
    • EndNote
    • BibTex
    • RefWorks
    Type
    Article
    Authors
    Schoedel, Alexander
    Boyette, Wesley
    Wojtas, Łukasz
    Eddaoudi, Mohamed cc
    Zaworotko, Michael J.
    KAUST Department
    Advanced Membranes and Porous Materials Research Center
    Chemical Science Program
    Functional Materials Design, Discovery and Development (FMD3)
    Physical Science and Engineering (PSE) Division
    KAUST Grant Number
    FIC/2010/06
    Date
    2013-09-11
    Online Publication Date
    2013-09-11
    Print Publication Date
    2013-09-25
    Permanent link to this record
    http://hdl.handle.net/10754/562982
    
    Metadata
    Show full item record
    Abstract
    A new and versatile class of metal-organic materials (MOMs) with augmented lonsdaleite-e (lon-e-a) topology is presented herein. This family of lon-e nets are built by pillaring of hexagonal two-dimensional kagomé (kag) lattices constructed from well-known [Zn2(CO2R)4] paddlewheel molecular building blocks (MBBs) connected by 1,3- benzenedicarboxylate (bdc2-) linkers. The pillars are [Cr 3(μ3-O)(RCO2)]6 trigonal prismatic primary MBBs decorated by six pyridyl moieties (tp-PMBB-1). The three-fold symmetry (D3h) of tp-PMBB-1 is complementary with the alternating orientation of the axial sites of the paddlewheel MBBs and enables triple cross-linking of the kag layers by each pillar. These MOMs represent the first examples of axial-to-axial pillared undulating kag layers, and they are readily fine-tuned because the bdc2- moieties can be varied at their 5-position without changing the overall structure. This lon-e platform possesses functionalized hexagonal channels since the kag lattices are necessarily eclipsed. The effects of the substituent at the 5-positions of the bdc 2- linkers upon gas adsorption, particularly the heats of adsorption of carbon dioxide and methane, were studied. © 2013 American Chemical Society.
    Sponsors
    This work is supported by Award No. FIC/2010/06, made by the King Abdullah University of Science and Technology (KAUST). The authors thank Prof. D. M. Proserpio (Universita stegli di Milano) for assistance with topological classification.
    Publisher
    American Chemical Society (ACS)
    Journal
    Journal of the American Chemical Society
    DOI
    10.1021/ja406030p
    Relations
    Is Supplemented By:
    • [Dataset]
      Schoedel, A., Boyette, W., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 969730: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc11k2m9. DOI: 10.5517/cc11k2m9 HANDLE: 10754/624273
    • [Dataset]
      Schoedel, A., Boyette, W., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 969731: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc11k2nb. DOI: 10.5517/cc11k2nb HANDLE: 10754/624274
    • [Dataset]
      Schoedel, A., Boyette, W., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 969732: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc11k2pc. DOI: 10.5517/cc11k2pc HANDLE: 10754/624275
    • [Dataset]
      Schoedel, A., Boyette, W., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 969733: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc11k2qd. DOI: 10.5517/cc11k2qd HANDLE: 10754/624276
    • [Dataset]
      Schoedel, A., Boyette, W., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 969734: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc11k2rf. DOI: 10.5517/cc11k2rf HANDLE: 10754/624277
    • [Dataset]
      Schoedel, A., Boyette, W., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 969735: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc11k2sg. DOI: 10.5517/cc11k2sg HANDLE: 10754/624278
    • [Dataset]
      Schoedel, A., Boyette, W., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 969736: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc11k2th. DOI: 10.5517/cc11k2th HANDLE: 10754/624279
    • [Dataset]
      Schoedel, A., Boyette, W., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 969737: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc11k2vj. DOI: 10.5517/cc11k2vj HANDLE: 10754/624280
    • [Dataset]
      Schoedel, A., Boyette, W., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 969738: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc11k2wk. DOI: 10.5517/cc11k2wk HANDLE: 10754/624281
    ae974a485f413a2113503eed53cd6c53
    10.1021/ja406030p
    Scopus Count
    Collections
    Articles; Advanced Membranes and Porous Materials Research Center; Physical Science and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3); Chemical Science Program

    entitlement

     
    DSpace software copyright © 2002-2021  DuraSpace
    Quick Guide | Contact Us | Send Feedback
    Open Repository is a service hosted by 
    Atmire NV
     

    Export search results

    The export option will allow you to export the current search results of the entered query to a file. Different formats are available for download. To export the items, click on the button corresponding with the preferred download format.

    By default, clicking on the export buttons will result in a download of the allowed maximum amount of items. For anonymous users the allowed maximum amount is 50 search results.

    To select a subset of the search results, click "Selective Export" button and make a selection of the items you want to export. The amount of items that can be exported at once is similarly restricted as the full export.

    After making a selection, click one of the export format buttons. The amount of items that will be exported is indicated in the bubble next to export format.