Complexation-tailored morphology of asymmetric block copolymer membranes
KAUST DepartmentAdvanced Membranes and Porous Materials Research Center
Biological and Environmental Sciences and Engineering (BESE) Division
Chemical Engineering Program
Environmental Science and Engineering Program
Nanostructured Polymeric Membrane Lab
Physical Science and Engineering (PSE) Division
Water Desalination and Reuse Research Center (WDRC)
Online Publication Date2013-07-15
Print Publication Date2013-08-14
Permanent link to this recordhttp://hdl.handle.net/10754/562906
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AbstractHydrogen-bond formation between polystyrene-b-poly (4-vinylpyridine) (PS-b-P4VP) block copolymer (BCP) and -OH/-COOH functionalized organic molecules was used to tune morphology of asymmetric nanoporous membranes prepared by simultaneous self-assembly and nonsolvent induced phase separation. The morphologies were characterized by field emmision scanning electron microscopy (FESEM) and atomic force microscopy (AFM). Hydrogen bonds were confirmed by infrared (IR), and the results were correlated to rheology characterization. The OH-functionalized organic molecules direct the morphology into hexagonal order. COOH-functionalized molecules led to both lamellar and hexagonal structures. Micelle formation in solutions and their sizes were determined using dynamic light scattering (DLS) measurements and water fluxes of 600-3200 L/m 2·h·bar were obtained. The pore size of the plain BCP membrane was smaller than with additives. The following series of additives led to pores with hexagonal order with increasing pore size: terephthalic acid (COOH-bifunctionalized) < rutin (OH-multifunctionalized) < 9-anthracenemethanol (OH-monofunctionalized) < 3,5-dihydroxybenzyl alcohol (OH-trifunctionalized). © 2013 American Chemical Society.
CitationMadhavan, P., Peinemann, K.-V., & Nunes, S. P. (2013). Complexation-Tailored Morphology of Asymmetric Block Copolymer Membranes. ACS Applied Materials & Interfaces, 5(15), 7152–7159. doi:10.1021/am401497m
PublisherAmerican Chemical Society (ACS)
CollectionsArticles; Biological and Environmental Sciences and Engineering (BESE) Division; Advanced Membranes and Porous Materials Research Center; Environmental Science and Engineering Program; Physical Science and Engineering (PSE) Division; Chemical Engineering Program; Water Desalination and Reuse Research Center (WDRC)
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