Preparation of fluorinated biaryls through direct palladium-catalyzed coupling of polyfluoroarenes with aryltrifluoroborates

Type
Article
Authors
Fang, Xin
Huang, Yuanyuan
Chen, Xiaoqing
Lin, Xiaoxi
Bai, Zhengshuai
Huang, Kuo-Wei cc
Yuan, Yaofeng
Weng, Zhiqiang
KAUST Department
Chemical Science Program
Homogeneous Catalysis Laboratory (HCL)
KAUST Catalysis Center (KCC)
Physical Science and Engineering (PSE) Division
Date
2013-07
Permanent link to this record
http://hdl.handle.net/10754/562833

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Abstract
The direct palladium-catalyzed coupling of polyfluoroarenes with aryltrifluoroborates gave the desired products of fluorinated biaryls in good to excellent yields. A diverse set of important functional groups including methoxy, aldehyde, ester, nitro and halide can be well tolerated in the protocol. © 2013 Elsevier B.V. All rights reserved.
Citation
Fang, X., Huang, Y., Chen, X., Lin, X., Bai, Z., Huang, K.-W., … Weng, Z. (2013). Preparation of fluorinated biaryls through direct palladium-catalyzed coupling of polyfluoroarenes with aryltrifluoroborates. Journal of Fluorine Chemistry, 151, 50–57. doi:10.1016/j.jfluchem.2013.03.017
Sponsors
We acknowledge the financial support from National Natural Science Foundation of China (21072030) and Fuzhou University (022318) to Z.W. and King Abdullah University of Science and Technology to K.-W. H.
Publisher
Elsevier BV
Journal
Journal of Fluorine Chemistry
DOI
10.1016/j.jfluchem.2013.03.017
Collections
Articles; Physical Science and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)