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    Steric and electronic parameters of a bulky yet flexible N-heterocyclic carbene: 1,3-bis(2,6-bis(1-ethylpropyl)phenyl)imidazol-2-ylidene (IPent)

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    Type
    Article
    Authors
    Collado, Alba
    Balogh, János
    Meiries, Sébastien
    Slawin, Alexandra M. Z.
    Falivene, Laura cc
    Cavallo, Luigi cc
    Nolan, Steven P. cc
    KAUST Department
    Chemical Science Program
    KAUST Catalysis Center (KCC)
    Physical Science and Engineering (PSE) Division
    Date
    2013-05-28
    Online Publication Date
    2013-05-28
    Print Publication Date
    2013-06-10
    Permanent link to this record
    http://hdl.handle.net/10754/562808
    
    Metadata
    Show full item record
    Abstract
    The free N-heterocyclic carbene IPent (1; IPent = 1,3-bis(2,6-bis(1- ethylpropyl)phenyl)imidazol-2-ylidene) was prepared from the corresponding imidazolium chloride salt (2). The steric and electronic parameters of 1 were determined by synthesis of the gold(I) chloride complex [Au(IPent)Cl] (3) and the nickel-carbonyl complex [Ni(IPent)(CO)3] (4), respectively. 3 and 4 were fully characterized by NMR spectroscopy, elemental analysis, and X-ray diffraction studies on single crystals. © 2013 American Chemical Society.
    Citation
    Collado, A., Balogh, J., Meiries, S., Slawin, A. M. Z., Falivene, L., Cavallo, L., & Nolan, S. P. (2013). Steric and Electronic Parameters of a Bulky yet Flexible N-Heterocyclic Carbene: 1,3-Bis(2,6-bis(1-ethylpropyl)phenyl)imidazol-2-ylidene (IPent). Organometallics, 32(11), 3249–3252. doi:10.1021/om400168b
    Sponsors
    The ERC (Advanced Investigator Award-FUNCAT), Umicore, Syngenta and the EPSRC are thanked for support of this work. We thank the EPSRC National Mass Spectrometry Service Center in Swansea for mass analyses. S.P.N. is a Royal Society Wolfson Research Merit Award holder.
    Publisher
    American Chemical Society (ACS)
    Journal
    Organometallics
    DOI
    10.1021/om400168b
    Relations
    Is Supplemented By:
    • [Dataset]
      Collado, A., Balogh, J., Meiries, S., Slawin, A. M. Z., Falivene, L., Cavallo, L., & Nolan, S. P. (2013). CCDC 926492: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1032v1. DOI: 10.5517/cc1032v1 HANDLE: 10754/624193
    • [Dataset]
      Collado, A., Balogh, J., Meiries, S., Slawin, A. M. Z., Falivene, L., Cavallo, L., & Nolan, S. P. (2013). CCDC 926491: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1032t0. DOI: 10.5517/cc1032t0 HANDLE: 10754/624192
    ae974a485f413a2113503eed53cd6c53
    10.1021/om400168b
    Scopus Count
    Collections
    Articles; Physical Science and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)

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