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    Charge ordering in reactive sputtered (1 0 0) and (1 1 1) oriented epitaxial Fe3O4 films

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    Type
    Article
    Authors
    Mi, Wenbo
    Guo, Zaibing
    Wang, Qingxiao
    Yang, Yang
    Bai, Haili
    KAUST Department
    Imaging and Characterization Core Lab
    Core Labs
    Date
    2013-06
    Permanent link to this record
    http://hdl.handle.net/10754/562782
    
    Metadata
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    Abstract
    Epitaxial Fe3O4 films with (1 0 0) and (1 1 1) orientations fabricated by reactive sputtering present simultaneous magnetic and electrical transitions at 120 and 124 K, respectively. The symmetry decreases from face-centered cubic to monoclinic structure across the Verwey transition. Extra spots with different brightness at different positions appear in selected-area diffraction patterns at 95 K. The extra spots come from the charge ordering of outer-layer electrons of Fe atoms, and should be related to the charge ordering of octahedral B-site Fe atoms. © 2013 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
    Citation
    Mi, W., Guo, Z., Wang, Q., Yang, Y., & Bai, H. (2013). Charge ordering in reactive sputtered (100) and (111) oriented epitaxial Fe3O4 films. Scripta Materialia, 68(12), 972–975. doi:10.1016/j.scriptamat.2013.02.050
    Sponsors
    This work was supported by the National Natural Foundation of China (51172126) and the Key Project of Natural Foundation of Tianjin City (12JCZDJC27100).
    Publisher
    Elsevier BV
    Journal
    Scripta Materialia
    DOI
    10.1016/j.scriptamat.2013.02.050
    ae974a485f413a2113503eed53cd6c53
    10.1016/j.scriptamat.2013.02.050
    Scopus Count
    Collections
    Articles; Imaging and Characterization Core Lab

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