A drift-diffusion-reaction model for excitonic photovoltaic bilayers: Photovoltaic bilayers: Asymptotic analysis and a 2D hdg finite element scheme
KAUST DepartmentComputer, Electrical and Mathematical Sciences and Engineering (CEMSE) Division
Applied Mathematics and Computational Science Program
KAUST Grant NumberKUK-I1-007-43
Preprint Posting Date2012-02-03
Permanent link to this recordhttp://hdl.handle.net/10754/562736
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AbstractWe present and discuss a mathematical model for the operation of bilayer organic photovoltaic devices. Our model couples drift-diffusion-recombination equations for the charge carriers (specifically, electrons and holes) with a reaction-diffusion equation for the excitons/polaron pairs and Poisson's equation for the self-consistent electrostatic potential. The material difference (i.e. the HOMO/LUMO gap) of the two organic substrates forming the bilayer device is included as a work-function potential. Firstly, we perform an asymptotic analysis of the scaled one-dimensional stationary state system: (i) with focus on the dynamics on the interface and (ii) with the goal of simplifying the bulk dynamics away from the interface. Secondly, we present a two-dimensional hybrid discontinuous Galerkin finite element numerical scheme which is very well suited to resolve: (i) the material changes, (ii) the resulting strong variation over the interface, and (iii) the necessary upwinding in the discretization of drift-diffusion equations. Finally, we compare the numerical results with the approximating asymptotics. © 2013 World Scientific Publishing Company.
CitationBRINKMAN, D., FELLNER, K., MARKOWICH, P. A., & WOLFRAM, M.-T. (2013). A DRIFT–DIFFUSION–REACTION MODEL FOR EXCITONIC PHOTOVOLTAIC BILAYERS: ASYMPTOTIC ANALYSIS AND A 2D HDG FINITE ELEMENT SCHEME. Mathematical Models and Methods in Applied Sciences, 23(05), 839–872. doi:10.1142/s0218202512500625
SponsorsThe authors acknowledge support from King Abdullah University of Science and Technology (KAUST) Award Number: KUK-I1-007-43. P. A. M. also acknowledges support from the Fondation Sciences Mathematique de Paris, in form of his Excellence Chair 2011, and from the Royal Society through his Wolfson Research Merit Award. M.-T.W. acknowledges financial support from the Austrian Science Foundation (FWF) via the Hertha Firnberg project TU56-N23. K. F. acknowledges the support of NaWi Graz.
PublisherWorld Scientific Pub Co Pte Lt