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dc.contributor.authorZhang, ZhenJie
dc.contributor.authorWojtas, Łukasz
dc.contributor.authorEddaoudi, Mohamed
dc.contributor.authorZaworotko, Michael J.
dc.date.accessioned2015-08-03T11:03:26Z
dc.date.available2015-08-03T11:03:26Z
dc.date.issued2013-04-24
dc.identifier.issn00027863
dc.identifier.doi10.1021/ja4015666
dc.identifier.urihttp://hdl.handle.net/10754/562727
dc.description.abstractWhen immersed in solutions containing Cu(II) cations, the microporous metal-organic material P11 ([Cd4(BPT)4]·[Cd(C 44H36N8)(S)]·[S], BPT = biphenyl-3,4′,5-tricarboxylate) undergoes a transformation of its [Cd 2(COO)6]2- molecular building blocks (MBBs) into novel tetranuclear [Cu4X2(COO)6(S) 2] MBBs to form P11-Cu. The transformation occurs in single-crystal to single-crystal fashion, and its stepwise mechanism was studied by varying the Cd2+/Cu2+ ratio of the solution in which crystals of P11 were immersed. P11-16/1 (Cd in framework retained, Cd in encapsulated porphyrins exchanged) and other intermediate phases were thereby isolated and structurally characterized. P11-16/1 and P11-Cu retain the microporosity of P11, and the relatively larger MBBs in P11-Cu permit a 20% unit cell expansion and afford a higher surface area and a larger pore size. © 2013 American Chemical Society.
dc.description.sponsorshipThis work was supported by Award FIC/2010/06 from King Abdullah University of Science and Technology. The data for P11-Cu were collected at the Advanced Photon Source on beamline 15ID-C of ChemMatCARS Sector 15, which is principally supported by the National Science Foundation/Department of Energy under Grant NSF/CHE-0822838. The Advanced Photon Source is supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under Contract DE-AC02-06CH11357.
dc.publisherAmerican Chemical Society (ACS)
dc.titleStepwise transformation of the molecular building blocks in a porphyrin-encapsulating metal-organic material
dc.typeArticle
dc.contributor.departmentChemical Science Program
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Division
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Center
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)
dc.identifier.journalJournal of the American Chemical Society
dc.contributor.institutionDepartment of Chemistry, University of South Florida, 4202 East Fowler Avenue, CHE205, Tampa, FL 33620, United States
kaust.personEddaoudi, Mohamed
dc.relation.isSupplementedByZhang, Z., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 954550: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1118y9
dc.relation.isSupplementedByDOI:10.5517/cc1118y9
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624248
dc.relation.isSupplementedByZhang, Z., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 954551: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1118zb
dc.relation.isSupplementedByDOI:10.5517/cc1118zb
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624249
dc.relation.isSupplementedByZhang, Z., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 954552: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc11190d
dc.relation.isSupplementedByDOI:10.5517/cc11190d
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624250
dc.relation.isSupplementedByZhang, Z., Gao, W.-Y., Wojtas, L., Ma, S., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 878574: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyh73r
dc.relation.isSupplementedByDOI:10.5517/ccyh73r
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624704


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