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    Stepwise transformation of the molecular building blocks in a porphyrin-encapsulating metal-organic material

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    Type
    Article
    Authors
    Zhang, Zhenjie
    Wojtas, Łukasz
    Eddaoudi, Mohamed cc
    Zaworotko, Michael J.
    KAUST Department
    Advanced Membranes and Porous Materials Research Center
    Chemical Science Program
    Functional Materials Design, Discovery and Development (FMD3)
    Physical Science and Engineering (PSE) Division
    Date
    2013-04-10
    Online Publication Date
    2013-04-10
    Print Publication Date
    2013-04-24
    Permanent link to this record
    http://hdl.handle.net/10754/562727
    
    Metadata
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    Abstract
    When immersed in solutions containing Cu(II) cations, the microporous metal-organic material P11 ([Cd4(BPT)4]·[Cd(C 44H36N8)(S)]·[S], BPT = biphenyl-3,4′,5-tricarboxylate) undergoes a transformation of its [Cd 2(COO)6]2- molecular building blocks (MBBs) into novel tetranuclear [Cu4X2(COO)6(S) 2] MBBs to form P11-Cu. The transformation occurs in single-crystal to single-crystal fashion, and its stepwise mechanism was studied by varying the Cd2+/Cu2+ ratio of the solution in which crystals of P11 were immersed. P11-16/1 (Cd in framework retained, Cd in encapsulated porphyrins exchanged) and other intermediate phases were thereby isolated and structurally characterized. P11-16/1 and P11-Cu retain the microporosity of P11, and the relatively larger MBBs in P11-Cu permit a 20% unit cell expansion and afford a higher surface area and a larger pore size. © 2013 American Chemical Society.
    Citation
    Zhang, Z., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2013). Stepwise Transformation of the Molecular Building Blocks in a Porphyrin-Encapsulating Metal–Organic Material. Journal of the American Chemical Society, 135(16), 5982–5985. doi:10.1021/ja4015666
    Sponsors
    This work was supported by Award FIC/2010/06 from King Abdullah University of Science and Technology. The data for P11-Cu were collected at the Advanced Photon Source on beamline 15ID-C of ChemMatCARS Sector 15, which is principally supported by the National Science Foundation/Department of Energy under Grant NSF/CHE-0822838. The Advanced Photon Source is supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under Contract DE-AC02-06CH11357.
    Publisher
    American Chemical Society (ACS)
    Journal
    Journal of the American Chemical Society
    DOI
    10.1021/ja4015666
    Relations
    Is Supplemented By:
    • [Dataset]
      Zhang, Z., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 954550: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1118y9. DOI: 10.5517/cc1118y9 HANDLE: 10754/624248
    • [Dataset]
      Zhang, Z., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 954551: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc1118zb. DOI: 10.5517/cc1118zb HANDLE: 10754/624249
    • [Dataset]
      Zhang, Z., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 954552: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc11190d. DOI: 10.5517/cc11190d HANDLE: 10754/624250
    • [Dataset]
      Zhang, Z., Gao, W.-Y., Wojtas, L., Ma, S., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 878574: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyh73r. DOI: 10.5517/ccyh73r HANDLE: 10754/624704
    ae974a485f413a2113503eed53cd6c53
    10.1021/ja4015666
    Scopus Count
    Collections
    Articles; Advanced Membranes and Porous Materials Research Center; Physical Science and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3); Chemical Science Program

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