Size-controlled fluorescent nanodiamonds: A facile method of fabrication and color-center counting
KAUST DepartmentFunctional Nanomaterials Lab (FuNL)
KAUST Catalysis Center (KCC)
KAUST Solar Center (KSC)
Materials Science and Engineering Program
Physical Sciences and Engineering (PSE) Division
KAUST Grant NumberFIC/2010/02
Permanent link to this recordhttp://hdl.handle.net/10754/562544
MetadataShow full item record
AbstractWe present a facile method for the production of fluorescent diamond nanocrystals (DNCs) of different sizes and efficiently quantify the concentration of emitting defect color centers (DCCs) of each DNC size. We prepared the DNCs by ball-milling commercially available micrometer-sized synthetic (high pressure, high temperature (HPHT)) diamonds and then separated the as-produced DNCs by density gradient ultracentrifugation (DGU) into size-controlled fractions. A protocol to enhance the uniformity of the nitrogen-vacancy (NV) centers in the diamonds was devised by depositing the DNCs as a dense monolayer on amino-silanized silicon substrates and then subjecting the monolayer to He+ beam irradiation. Using a standard confocal setup, we analyzed the average number of NV centers per crystal, and obtained a quantitative relationship between the DNC particle size and the NV number per crystal. This relationship was in good agreement with results from previous studies that used more elaborate setups. Our findings suggest that nanocrystal size separation by DGU may be used to control the number of defects per nanocrystal. The efficient approaches described herein to control and quantify DCCs are valuable to researchers as they explore applications for color centers and new strategies to create them. © 2013 The Royal Society of Chemistry.
SponsorsThe authors acknowledge the financial support of the Office of Competitive Research Funds (OCRF) at King Abdullah University of Science and Technology (KAUST) under the "Competitive Research Grant" (CRG) program no. FIC/2010/02. ML and DLF also acknowledge support from the Schlumberger-Doll Research Center.
PublisherRoyal Society of Chemistry (RSC)
- Creation of high density ensembles of nitrogen-vacancy centers in nitrogen-rich type Ib nanodiamonds.
- Authors: Su LJ, Fang CY, Chang YT, Chen KM, Yu YC, Hsu JH, Chang HC
- Issue date: 2013 Aug 9
- Scalable fabrication of high purity diamond nanocrystals with long-spin-coherence nitrogen vacancy centers.
- Authors: Trusheim ME, Li L, Laraoui A, Chen EH, Bakhru H, Schröder T, Gaathon O, Meriles CA, Englund D
- Issue date: 2014 Jan 8
- Monodisperse Five-Nanometer-Sized Detonation Nanodiamonds Enriched in Nitrogen-Vacancy Centers.
- Authors: Terada D, Segawa TF, Shames AI, Onoda S, Ohshima T, O Sawa E, Igarashi R, Shirakawa M
- Issue date: 2019 Jun 25
- Stimulated emission depletion microscopy resolves individual nitrogen vacancy centers in diamond nanocrystals.
- Authors: Arroyo-Camejo S, Adam MP, Besbes M, Hugonin JP, Jacques V, Greffet JJ, Roch JF, Hell SW, Treussart F
- Issue date: 2013 Dec 23
- Fluorescence and spin properties of defects in single digit nanodiamonds.
- Authors: Tisler J, Balasubramanian G, Naydenov B, Kolesov R, Grotz B, Reuter R, Boudou JP, Curmi PA, Sennour M, Thorel A, Börsch M, Aulenbacher K, Erdmann R, Hemmer PR, Jelezko F, Wrachtrup J
- Issue date: 2009 Jul 28