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dc.contributor.authorLee, S. Y Tina
dc.contributor.authorGhani, Amylia Abdul
dc.contributor.authorD’Elia, Valerio
dc.contributor.authorCokoja, Mirza
dc.contributor.authorHerrmann, Wolfgang A.
dc.contributor.authorBasset, Jean-Marie
dc.contributor.authorKühn, Fritz
dc.date.accessioned2015-08-03T10:41:46Z
dc.date.available2015-08-03T10:41:46Z
dc.date.issued2013
dc.identifier.issn11440546
dc.identifier.doi10.1039/c3nj00693j
dc.identifier.urihttp://hdl.handle.net/10754/562536
dc.description.abstractRing opening of various nickela- and palladalactones induced by the cleavage of the M-O bond by methyl trifluoromethanesulfonate (MeOTf) and methyl iodide (MeI) is examined. Experimental evidence supports the mechanism of ring opening by the alkylating agent followed by β-H elimination leading to methyl acrylate and a metal-hydride species. MeOTf shows by far higher efficiency in the lactone ring opening than any other methylating agent including the previously reported methyl iodide. © 2013 The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.
dc.publisherRoyal Society of Chemistry (RSC)
dc.titleLiberation of methyl acrylate from metallalactone complexes via M-O ring opening (M = Ni, Pd) with methylation agents
dc.typeArticle
dc.contributor.departmentChemical Science Program
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalNew Journal of Chemistry
dc.contributor.institutionDepartment of Inorganic Chemistry/Molecular Catalysis, Catalysis Research Center, Technische Universität München, Ernst-Otto-Fischer-Straße 1, D-85747 Garching bei München, Germany
kaust.personD'Elia, Valerio
kaust.personBasset, Jean-Marie
kaust.personLee, S. Y Tina
kaust.personGhani, Amylia Abdul


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