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    Liberation of methyl acrylate from metallalactone complexes via M-O ring opening (M = Ni, Pd) with methylation agents

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    Type
    Article
    Authors
    Lee, S. Y Tina
    Ghani, Amylia Abdul
    D’Elia, Valerio cc
    Cokoja, Mirza
    Herrmann, Wolfgang A.
    Basset, Jean-Marie cc
    Kühn, Fritz
    KAUST Department
    Chemical Science Program
    KAUST Catalysis Center (KCC)
    Physical Science and Engineering (PSE) Division
    Date
    2013
    Permanent link to this record
    http://hdl.handle.net/10754/562536
    
    Metadata
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    Abstract
    Ring opening of various nickela- and palladalactones induced by the cleavage of the M-O bond by methyl trifluoromethanesulfonate (MeOTf) and methyl iodide (MeI) is examined. Experimental evidence supports the mechanism of ring opening by the alkylating agent followed by β-H elimination leading to methyl acrylate and a metal-hydride species. MeOTf shows by far higher efficiency in the lactone ring opening than any other methylating agent including the previously reported methyl iodide. © 2013 The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.
    Citation
    Lee, S. Y. T., Ghani, A. A., D’Elia, V., Cokoja, M., Herrmann, W. A., Basset, J.-M., & Kühn, F. E. (2013). Liberation of methyl acrylate from metallalactone complexes via M–O ring opening (M = Ni, Pd) with methylation agents. New Journal of Chemistry, 37(11), 3512. doi:10.1039/c3nj00693j
    Publisher
    Royal Society of Chemistry (RSC)
    Journal
    New Journal of Chemistry
    DOI
    10.1039/c3nj00693j
    ae974a485f413a2113503eed53cd6c53
    10.1039/c3nj00693j
    Scopus Count
    Collections
    Articles; Physical Science and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)

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