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TCNQ-embedded heptacene and nonacene: Synthesis, characterization and physical properties

dc.contributor.authorYe, Qun
dc.contributor.authorChang, Jingjing
dc.contributor.authorHuang, Kuo-Wei
dc.contributor.authorDai, Gaole
dc.contributor.authorChi, Chunyan
dc.date.accessioned2015-08-03T10:41:27Z
dc.date.available2015-08-03T10:41:27Z
dc.date.issued2013
dc.identifier.citationYe, Q., Chang, J., Huang, K.-W., Dai, G., & Chi, C. (2013). TCNQ-embedded heptacene and nonacene: synthesis, characterization and physical properties. Organic & Biomolecular Chemistry, 11(37), 6285. doi:10.1039/c3ob40796a
dc.identifier.issn14770520
dc.identifier.doi10.1039/c3ob40796a
dc.identifier.urihttp://hdl.handle.net/10754/562527
dc.description.abstractIncorporation of 7,7,8,8-tetracyanoquinodimethane (TCNQ) moieties into the acene backbone has been successfully achieved and two heptacene-TCNQ derivatives and one nonacene-TCNQ derivative have been synthesized and well characterized. Two TCNQ moieties have been embedded into heptacene and nonacene backbones for the first time. All the three compounds have good stability and solubility due to the presence of TCNQ moieties. Single crystal analysis revealed a bent butterfly-like conformation of these molecules. Their charge transport properties have been characterized using organic field effect transistors (OFETs). © 2013 The Royal Society of Chemistry.
dc.description.sponsorshipThis work was financially supported by Singapore MOE AcRF grant R-143-000-510-112 (C. C.), NUS Start Up grant R-143-000-486-133 (C. C.) and KAUST (K.-W. H.). We thank Mdm. Tan Geok Kheng for the crystallographic analysis.
dc.publisherRoyal Society of Chemistry (RSC)
dc.titleTCNQ-embedded heptacene and nonacene: Synthesis, characterization and physical properties
dc.typeArticle
dc.contributor.departmentChemical Science Program
dc.contributor.departmentHomogeneous Catalysis Laboratory (HCL)
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalOrganic & Biomolecular Chemistry
dc.contributor.institutionDepartment of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543, Singapore
kaust.personHuang, Kuo-Wei
dc.relation.issupplementedbyDOI:10.5517/cc10cslr
dc.relation.issupplementedbyDOI:10.5517/cc10cskq
display.relations<b> Is Supplemented By:</b> <br/> <ul><li><i>[Dataset]</i> <br/> Ye, Q., Chang, J., Huang, K.-W., Dai, G., & Chi, C. (2013). CCDC 934854: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc10cslr. DOI: <a href="https://doi.org/10.5517/cc10cslr">10.5517/cc10cslr</a> HANDLE: <a href="http://hdl.handle.net/10754/624214">10754/624214</a></li><li><i>[Dataset]</i> <br/> Ye, Q., Chang, J., Huang, K.-W., Dai, G., & Chi, C. (2013). CCDC 934853: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc10cskq. DOI: <a href="https://doi.org/10.5517/cc10cskq">10.5517/cc10cskq</a> HANDLE: <a href="http://hdl.handle.net/10754/624213">10754/624213</a></li></ul>


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