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    Two-step crystal engineering of porous nets from [Cr3(μ 3-O)(RCO2)6] and [Cu3(μ 3-Cl)(RNH2)6Cl6] molecular building blocks

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    Type
    Article
    Authors
    Elsaidi, Sameh K.
    Mohamed, Mona Hassan
    Wojtas, Łukasz
    Cairns, Amy
    Eddaoudi, Mohamed cc
    Zaworotko, Michael J.
    KAUST Department
    Advanced Membranes and Porous Materials Research Center
    Chemical Science Program
    Functional Materials Design, Discovery and Development (FMD3)
    Physical Science and Engineering (PSE) Division
    Date
    2013
    Permanent link to this record
    http://hdl.handle.net/10754/562524
    
    Metadata
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    Abstract
    Two porous nets have been prepared via a 2-step crystal engineering approach that links decorated trigonal prismatic [Cr3(μ 3-O)(CO2)6] and [Cu3(μ 3-Cl)(RNH2)6Cl6] molecular building blocks, MBBs. tp-PMBB-5-acs-1 is a rare example of a rigid acs underlying net whereas tp-PMBB-6-stp-1, an stp underlying net, exhibits free NH2 groups in its channels and a relatively high isosteric heat of adsorption for CO2. © 2013 The Royal Society of Chemistry.
    Citation
    Elsaidi, S. K., Mohamed, M. H., Wojtas, L., Cairns, A. J., Eddaoudi, M., & Zaworotko, M. J. (2013). Two-step crystal engineering of porous nets from [Cr3(μ3-O)(RCO2)6] and [Cu3(μ3-Cl)(RNH2)6Cl6] molecular building blocks. Chemical Communications, 49(74), 8154. doi:10.1039/c3cc44133d
    Publisher
    Royal Society of Chemistry (RSC)
    Journal
    Chemical Communications
    DOI
    10.1039/c3cc44133d
    PubMed ID
    23925067
    Relations
    Is Supplemented By:
    • [Dataset]
      Elsaidi, S. K., Mohamed, M. H., Wojtas, L., Cairns, A. J., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 943023: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc10n932. DOI: 10.5517/cc10n932 HANDLE: 10754/624230
    • [Dataset]
      Elsaidi, S. K., Mohamed, M. H., Wojtas, L., Cairns, A. J., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 943025: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc10n954. DOI: 10.5517/cc10n954 HANDLE: 10754/624232
    • [Dataset]
      Elsaidi, S. K., Mohamed, M. H., Wojtas, L., Cairns, A. J., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 943024: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc10n943. DOI: 10.5517/cc10n943 HANDLE: 10754/624231
    ae974a485f413a2113503eed53cd6c53
    10.1039/c3cc44133d
    Scopus Count
    Collections
    Articles; Advanced Membranes and Porous Materials Research Center; Physical Science and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3); Chemical Science Program

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