Two-step crystal engineering of porous nets from [Cr3(μ 3-O)(RCO2)6] and [Cu3(μ 3-Cl)(RNH2)6Cl6] molecular building blocks
Type
ArticleAuthors
Elsaidi, Sameh K.Mohamed, Mona Hassan
Wojtas, Łukasz
Cairns, Amy
Eddaoudi, Mohamed
Zaworotko, Michael J.
KAUST Department
Advanced Membranes and Porous Materials Research CenterChemical Science Program
Functional Materials Design, Discovery and Development (FMD3)
Physical Science and Engineering (PSE) Division
Date
2013Permanent link to this record
http://hdl.handle.net/10754/562524Metadata
Show full item recordAbstract
Two porous nets have been prepared via a 2-step crystal engineering approach that links decorated trigonal prismatic [Cr3(μ 3-O)(CO2)6] and [Cu3(μ 3-Cl)(RNH2)6Cl6] molecular building blocks, MBBs. tp-PMBB-5-acs-1 is a rare example of a rigid acs underlying net whereas tp-PMBB-6-stp-1, an stp underlying net, exhibits free NH2 groups in its channels and a relatively high isosteric heat of adsorption for CO2. © 2013 The Royal Society of Chemistry.Publisher
Royal Society of Chemistry (RSC)Journal
Chemical CommunicationsPubMed ID
23925067Relations
Is Supplemented By:- [Dataset]
Elsaidi, S. K., Mohamed, M. H., Wojtas, L., Cairns, A. J., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 943023: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc10n932. DOI: 10.5517/cc10n932 HANDLE: 10754/624230 - [Dataset]
Elsaidi, S. K., Mohamed, M. H., Wojtas, L., Cairns, A. J., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 943025: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc10n954. DOI: 10.5517/cc10n954 HANDLE: 10754/624232 - [Dataset]
Elsaidi, S. K., Mohamed, M. H., Wojtas, L., Cairns, A. J., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 943024: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc10n943. DOI: 10.5517/cc10n943 HANDLE: 10754/624231