A facile metal-free "grafting-from" route from acrylamide-based substrate toward complex macromolecular combs
KAUST DepartmentKAUST Catalysis Center (KCC)
Physical Sciences and Engineering (PSE) Division
Chemical Science Program
Polymer Synthesis Laboratory
Permanent link to this recordhttp://hdl.handle.net/10754/562520
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AbstractHigh-molecular-weight poly(N,N-dimethylacrylamide-co-acrylamide) was used as a model functional substrate to investigate phosphazene base (t-BuP 4)-promoted metal-free anionic graft polymerization utilizing primary amide moieties as initiating sites. The (co)polymerization of epoxides was proven to be effective, leading to macromolecular combs with side chains being single- or double-graft homopolymer, block copolymer and statistical copolymer. © 2013 The Royal Society of Chemistry.
PublisherRoyal Society of Chemistry
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