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    A single source precursor route to group 13 homo- and heterometallic oxides as highly active supports for gold-catalyzed aerobic epoxidation of trans-stilbene

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    Type
    Article
    Authors
    Mishra, Shashank K.
    Mendez, Violaine
    Jeanneau, Erwann
    Caps, Valerie cc
    Danièle, Stéphane
    KAUST Department
    KAUST Catalysis Center (KCC)
    Date
    2012-12-14
    Online Publication Date
    2012-12-14
    Print Publication Date
    2013-02-01
    Permanent link to this record
    http://hdl.handle.net/10754/562458
    
    Metadata
    Show full item record
    Abstract
    A new Mitsubishi-type of star-shaped homoleptic derivative of indium(III), In4(mdea)6 (2, mdeaH2 = N-methyldiethanolamine) , was synthesized by the chloro-aminoalkoxo exchange reaction of a heteroleptic complex In6Cl6(mdea)6 (1) and used as a facile single source molecular precursor for the sol-gel preparation of high surface area indium oxide. Successful deposition of gold nanoparticles (1 wt.-%) of average size 3.3 nm on the above metal oxide by using HAuCl4· 3H2O afforded a highly efficient Au/In2O3 catalyst for the aerobic epoxidation of trans-stilbene at low temperature. The above single source precursor approach was further extended to obtain other group 13 homo- and heterometallic oxides, namely, α-Ga2O 3, β-Ga2O3 and Al4Ga 2O9, as highly active supports for gold catalysts. The obtained Au/M2O3 (M = Ga, In) and Au/Al4Ga 2O9 catalysts were thoroughly characterized by using several physicochemical techniques such as XRD, high resolution transmission electron microscopy (HR-TEM), energy-dispersive X-ray (EDX) spectroscopy, and X-ray photoelectron spectroscopy (XPS). A comparative study of the above catalysts for the model aerobic oxidation of stilbene in methylcyclohexane was undertaken. Highly efficient catalysts for aerobic oxidation reactions were obtained by depositing gold nanoparticles on group 13 mono- or mixed metal oxides prepared from the hydrolysis of well-characterized homo- and heterometallic N-methyldiethanolaminate derivatives. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
    Citation
    Mishra, S., Mendez, V., Jeanneau, E., Caps, V., & Daniele, S. (2012). A Single Source Precursor Route to Group 13 Homo- and Heterometallic Oxides as Highly Active Supports for Gold-Catalyzed Aerobic Epoxidation oftrans-Stilbene. European Journal of Inorganic Chemistry, 2013(4), 500–510. doi:10.1002/ejic.201201191
    Publisher
    Wiley
    Journal
    European Journal of Inorganic Chemistry
    DOI
    10.1002/ejic.201201191
    ae974a485f413a2113503eed53cd6c53
    10.1002/ejic.201201191
    Scopus Count
    Collections
    Articles; KAUST Catalysis Center (KCC)

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