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dc.contributor.authorWeng, Zhiqiang
dc.contributor.authorHe, Weiming
dc.contributor.authorChen, Chaohuang
dc.contributor.authorLee, Richmond
dc.contributor.authorTan, Davin
dc.contributor.authorLai, Zhiping
dc.contributor.authorKong, Dedao
dc.contributor.authorYuan, Yaofeng
dc.contributor.authorHuang, Kuo-Wei
dc.date.accessioned2015-08-03T10:38:53Z
dc.date.available2015-08-03T10:38:53Z
dc.date.issued2012-12-12
dc.identifier.citationWeng, Z., He, W., Chen, C., Lee, R., Tan, D., Lai, Z., … Huang, K.-W. (2012). An Air-Stable Copper Reagent for Nucleophilic Trifluoromethylthiolation of Aryl Halides. Angewandte Chemie International Edition, 52(5), 1548–1552. doi:10.1002/anie.201208432
dc.identifier.issn14337851
dc.identifier.pmid23239429
dc.identifier.doi10.1002/anie.201208432
dc.identifier.urihttp://hdl.handle.net/10754/562457
dc.description.abstractA series of copper(I) trifluoromethyl thiolate complexes have been synthesized from the reaction of CuF2 with Me3SiCF 3 and S8 (see scheme; Cu red, F green, N blue, S yellow). These air-stable complexes serve as reagents for the efficient conversion of a wide range of aryl halides into the corresponding aryl trifluoromethyl thioethers in excellent yields. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
dc.description.sponsorshipWe thank Prof. John Hartwig for useful discussions. The financial support from National Natural Science Foundation of China (21072030) and Fuzhou University (022318) to Z.W. and KAUST to K.-W.H. are acknowledged.
dc.publisherWiley
dc.subjectC-S bonds
dc.subjectcopper
dc.subjectcross-coupling
dc.subjecttrifluoromethylthiolation
dc.titleAn air-stable copper reagent for nucleophilic trifluoromethylthiolation of aryl halides
dc.typeArticle
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Center
dc.contributor.departmentChemical Engineering Program
dc.contributor.departmentChemical Science Program
dc.contributor.departmentHomogeneous Catalysis Laboratory (HCL)
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalAngewandte Chemie International Edition
dc.contributor.institutionDepartment of Chemistry, Fujian Provincial Key Laboratory of Photocatalysis, Fuzhou University, Fuzhou 350002, China
kaust.personLee, Richmond
kaust.personTan, Davin
kaust.personLai, Zhiping
kaust.personHuang, Kuo-Wei
dc.relation.issupplementedbyDOI:10.5517/ccz752f
dc.relation.issupplementedbyDOI:10.5517/ccz751d
dc.relation.issupplementedbyDOI:10.5517/ccz750c
dc.relation.issupplementedbyDOI:10.5517/ccz74z9
display.relations<b> Is Supplemented By:</b> <br/> <ul><li><i>[Dataset]</i> <br/> Weng, Z., He, W., Chen, C., Lee, R., Tan, D., Lai, Z., … Huang, K.-W. (2013). CCDC 900614: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccz752f. DOI: <a href="https://doi.org/10.5517/ccz752f">10.5517/ccz752f</a> HANDLE: <a href="http://hdl.handle.net/10754/624751">10754/624751</a></li><li><i>[Dataset]</i> <br/> Weng, Z., He, W., Chen, C., Lee, R., Tan, D., Lai, Z., … Huang, K.-W. (2013). CCDC 900613: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccz751d. DOI: <a href="https://doi.org/10.5517/ccz751d">10.5517/ccz751d</a> HANDLE: <a href="http://hdl.handle.net/10754/624750">10754/624750</a></li><li><i>[Dataset]</i> <br/> Weng, Z., He, W., Chen, C., Lee, R., Tan, D., Lai, Z., … Huang, K.-W. (2013). CCDC 900612: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccz750c. DOI: <a href="https://doi.org/10.5517/ccz750c">10.5517/ccz750c</a> HANDLE: <a href="http://hdl.handle.net/10754/624749">10754/624749</a></li><li><i>[Dataset]</i> <br/> Weng, Z., He, W., Chen, C., Lee, R., Tan, D., Lai, Z., … Huang, K.-W. (2013). CCDC 900611: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccz74z9. DOI: <a href="https://doi.org/10.5517/ccz74z9">10.5517/ccz74z9</a> HANDLE: <a href="http://hdl.handle.net/10754/624748">10754/624748</a></li></ul>
dc.date.published-online2012-12-12
dc.date.published-print2013-01-28


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