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    An air-stable copper reagent for nucleophilic trifluoromethylthiolation of aryl halides

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    Type
    Article
    Authors
    Weng, Zhiqiang
    He, Weiming
    Chen, Chaohuang
    Lee, Richmond
    Tan, Davin
    Lai, Zhiping cc
    Kong, Dedao
    Yuan, Yaofeng
    Huang, Kuo-Wei cc
    KAUST Department
    Advanced Membranes and Porous Materials Research Center
    Chemical Engineering Program
    Chemical Science Program
    Homogeneous Catalysis Laboratory (HCL)
    KAUST Catalysis Center (KCC)
    Physical Science and Engineering (PSE) Division
    Date
    2012-12-12
    Online Publication Date
    2012-12-12
    Print Publication Date
    2013-01-28
    Permanent link to this record
    http://hdl.handle.net/10754/562457
    
    Metadata
    Show full item record
    Abstract
    A series of copper(I) trifluoromethyl thiolate complexes have been synthesized from the reaction of CuF2 with Me3SiCF 3 and S8 (see scheme; Cu red, F green, N blue, S yellow). These air-stable complexes serve as reagents for the efficient conversion of a wide range of aryl halides into the corresponding aryl trifluoromethyl thioethers in excellent yields. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
    Citation
    Weng, Z., He, W., Chen, C., Lee, R., Tan, D., Lai, Z., … Huang, K.-W. (2012). An Air-Stable Copper Reagent for Nucleophilic Trifluoromethylthiolation of Aryl Halides. Angewandte Chemie International Edition, 52(5), 1548–1552. doi:10.1002/anie.201208432
    Sponsors
    We thank Prof. John Hartwig for useful discussions. The financial support from National Natural Science Foundation of China (21072030) and Fuzhou University (022318) to Z.W. and KAUST to K.-W.H. are acknowledged.
    Publisher
    Wiley
    Journal
    Angewandte Chemie
    DOI
    10.1002/anie.201208432
    PubMed ID
    23239429
    Relations
    Is Supplemented By:
    • [Dataset]
      Weng, Z., He, W., Chen, C., Lee, R., Tan, D., Lai, Z., … Huang, K.-W. (2013). CCDC 900614: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccz752f. DOI: 10.5517/ccz752f HANDLE: 10754/624751
    • [Dataset]
      Weng, Z., He, W., Chen, C., Lee, R., Tan, D., Lai, Z., … Huang, K.-W. (2013). CCDC 900613: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccz751d. DOI: 10.5517/ccz751d HANDLE: 10754/624750
    • [Dataset]
      Weng, Z., He, W., Chen, C., Lee, R., Tan, D., Lai, Z., … Huang, K.-W. (2013). CCDC 900612: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccz750c. DOI: 10.5517/ccz750c HANDLE: 10754/624749
    • [Dataset]
      Weng, Z., He, W., Chen, C., Lee, R., Tan, D., Lai, Z., … Huang, K.-W. (2013). CCDC 900611: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccz74z9. DOI: 10.5517/ccz74z9 HANDLE: 10754/624748
    ae974a485f413a2113503eed53cd6c53
    10.1002/anie.201208432
    Scopus Count
    Collections
    Articles; Advanced Membranes and Porous Materials Research Center; Physical Science and Engineering (PSE) Division; Chemical Science Program; Chemical Engineering Program; KAUST Catalysis Center (KCC)

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