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    Water-soluble diphosphadiazacyclooctanes as ligands for aqueous organometallic catalysis

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    Type
    Article
    Authors
    Boulanger, Jérôme
    Bricout, Hervé
    Tilloy, Sébastien
    Fihri, Aziz
    Len, Christophe
    Hapiot, Frédéric
    Monflier, Éric
    KAUST Department
    KAUST Catalysis Center (KCC)
    Date
    2012-12
    Permanent link to this record
    http://hdl.handle.net/10754/562435
    
    Metadata
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    Abstract
    Two new water-soluble diphosphacyclooctanes been synthesized and characterized by NMR and surface tension measurements. Both phosphanes proved to coordinate rhodium in a very selective way as well-defined bidentates were obtained. When used in Rh-catalyzed hydroformylation of terminal alkenes, both ligands positively impacted the reaction chemoselectivity. © 2012 Elsevier B.V.
    Sponsors
    This work was supported by the Centre National de la Recherche Scientifique (CNRS).
    Publisher
    Elsevier BV
    Journal
    Catalysis Communications
    ISSN
    15667367
    DOI
    10.1016/j.catcom.2012.09.019
    ae974a485f413a2113503eed53cd6c53
    10.1016/j.catcom.2012.09.019
    Scopus Count
    Collections
    Articles; KAUST Catalysis Center (KCC)

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