Water-soluble diphosphadiazacyclooctanes as ligands for aqueous organometallic catalysis
Type
ArticleAuthors
Boulanger, JérômeBricout, Hervé
Tilloy, Sébastien
Fihri, Aziz
Len, Christophe
Hapiot, Frédéric
Monflier, Éric
KAUST Department
KAUST Catalysis Center (KCC)Date
2012-12Permanent link to this record
http://hdl.handle.net/10754/562435
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Two new water-soluble diphosphacyclooctanes been synthesized and characterized by NMR and surface tension measurements. Both phosphanes proved to coordinate rhodium in a very selective way as well-defined bidentates were obtained. When used in Rh-catalyzed hydroformylation of terminal alkenes, both ligands positively impacted the reaction chemoselectivity. © 2012 Elsevier B.V.Sponsors
This work was supported by the Centre National de la Recherche Scientifique (CNRS).Publisher
Elsevier BVJournal
Catalysis Communicationsae974a485f413a2113503eed53cd6c53
10.1016/j.catcom.2012.09.019