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dc.contributor.authorEspinas, Jeff
dc.contributor.authorPelletier, Jeremie
dc.contributor.authorAbou-Hamad, Edy
dc.contributor.authorEmsley, Lyndon
dc.contributor.authorBasset, Jean-Marie
dc.date.accessioned2015-08-03T10:37:12Z
dc.date.available2015-08-03T10:37:12Z
dc.date.issued2012-11-12
dc.identifier.issn02767333
dc.identifier.doi10.1021/om300918v
dc.identifier.urihttp://hdl.handle.net/10754/562410
dc.description.abstractA well-defined silica-based material with a homogeneous nanolayer presenting identical pairs of vicinal silanols has been prepared by reaction of the surface organometallic species [≡SiOZr(CH 2CMe 3) 3], obtained on a silica dehydroxylated at 900 °C, with the double-decker-shaped silsesquioxane (OH) 2DD(OH) 2. The surface structure has been established using extensive NMR characterization ( 1H, 13C, 29Si, HETCOR, double-quantum, triple-quantum). Treatment with Zr(CH 2CMe 3) 4 leads to the first well-defined single-site bipodal grafted bis-neopentyl zirconium complex. © 2012 American Chemical Society.
dc.publisherAmerican Chemical Society (ACS)
dc.titleA silica-supported double-decker silsesquioxane provides a second skin for the selective generation of bipodal surface organometallic complexes
dc.typeArticle
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Division
dc.contributor.departmentChemical Science Program
dc.identifier.journalOrganometallics
dc.contributor.institutionInstitut de Sciences Analytiques, Centre de RMN À Très Hauts Champs, Université de Lyon, 69100 Villeurbanne, France
kaust.personEspinas, Jeff
kaust.personPelletier, Jeremie
kaust.personAbou-Hamad, Edy
kaust.personBasset, Jean-Marie


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