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dc.contributor.authorChen, Yin
dc.contributor.authorCallens, Emmanuel
dc.contributor.authorAbou-Hamad, Edy
dc.contributor.authorMerle, Nicolas
dc.contributor.authorWhite, Andrew J P
dc.contributor.authorTaoufik, Mostafa
dc.contributor.authorCopéret, Christophe
dc.contributor.authorLe Roux, Erwan
dc.contributor.authorBasset, Jean-Marie
dc.date.accessioned2015-08-03T10:02:48Z
dc.date.available2015-08-03T10:02:48Z
dc.date.issued2012-10-22
dc.identifier.issn14337851
dc.identifier.pmid23090868
dc.identifier.doi10.1002/anie.201206272
dc.identifier.urihttp://hdl.handle.net/10754/562370
dc.description.abstractOn the surface of it: In the absence of co-catalyst, a well-defined silica-supported surface organometallic complex [(≢SiO)Ta VCl2Me2] selectively catalyzes the oligomerization of ethylene. The use of surface organometallic species allows three different pathways to be determined for the reduction of TaV to TaIII species under pressure of ethylene. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
dc.description.sponsorshipWe are indebted to Prof. Lyndon Emsley for his enthusiastic discussion and suggestions. The work is supported by KAUST and SABIC.
dc.publisherWiley
dc.subjectethylene
dc.subjectoligomerization
dc.subjectorganometallic compounds
dc.subjectsurface reactions
dc.subjecttantalum
dc.title[(≢SiO)TaVCl2Me2]: A well-defined silica-supported tantalum(V) surface complex as catalyst precursor for the selective cocatalyst-free trimerization of ethylene
dc.typeArticle
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Division
dc.contributor.departmentChemical Science Program
dc.contributor.departmentKAUST Solar Center (KSC)
dc.identifier.journalAngewandte Chemie International Edition
dc.contributor.institutionChimie Organometallique de Surface, Laboratoire de Chimie, ESCPE Lyon, F-308-43 Boulevard du 11 Novembre 1918, F-69616, Villeurbanne Cedex, France
dc.contributor.institutionDepartment of Chemistry, Imperial College London, Exhibition Road, London SW7 2AZ, United Kingdom
dc.contributor.institutionDepartment of Chemistry, University of Bergen, Realfagbygget, Allegaten 41, 5007, Bergen, Norway
dc.contributor.institutionDepartment of Chemistry, ETH Zurich, HCI H 229 Wolfgang-Pauli-Strasse 10, 8093, Zurich, Switzerland
kaust.personChen, Yin
kaust.personCallens, Emmanuel
kaust.personAbou-Hamad, Edy
kaust.personBasset, Jean-Marie
dc.relation.isSupplementedByChen, Y., Callens, E., Abou-Hamad, E., Merle, N., White, A. J. P., Taoufik, M., … Basset, J.-M. (2013). CCDC 870534: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccy6vrq
dc.relation.isSupplementedByDOI:10.5517/ccy6vrq
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624686


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