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dc.contributor.authorTomah Al-Masri, Harbi
dc.contributor.authorEmwas, Abdul-Hamid M.
dc.contributor.authorAl-Talla, Zeyad
dc.contributor.authorAl Kordi, Mohamed
dc.date.accessioned2015-08-03T09:59:33Z
dc.date.available2015-08-03T09:59:33Z
dc.date.issued2012-09
dc.identifier.issn10426507
dc.identifier.doi10.1080/10426507.2012.668985
dc.identifier.urihttp://hdl.handle.net/10754/562290
dc.description.abstractThe reaction of 1-naphthylamine with one equivalent of chlorodiphenylphosphine in the presence of triethylamine gave the (1-NHC 10H 7)PPh 2 (1) ligand. Refluxing of 1 with elemental sulfur or grey selenium in toluene (1:1 molar ratio) afforded (1-NHC 10H 7)P(S)Ph 2 (2) and (1-NHC 10H 7)P(Se)Ph 2 (3), respectively. Moreover, the byproduct {Ph 2P(S)} 2O (4) was isolated from the reaction of 1 with elemental sulfur. Compounds 1-3 were identified and characterized by multinuclear ( 1H, 13C, 31P, 77Se) NMR spectroscopy, mass spectrometry, and elemental analysis. Crystal structure determinations of 3 and 4 were carried out. Copyright © 2012 Taylor and Francis Group, LLC.
dc.publisherInforma UK Limited
dc.subjectAminophosphine
dc.subjectchalcogenides
dc.subjectchlorodiphenylphosphine
dc.subjectmolecular structure
dc.subjectphosphine
dc.titleSynthesis and characterization of new N-(diphenylphosphino)-naphthylamine chalcogenides: X-ray structures of (1-NHC 10H 7)P(Se)Ph 2 and Ph 2P(S)OP(S)Ph 2
dc.typeArticle
dc.contributor.departmentImaging and Characterization Core Lab
dc.contributor.departmentAnalytical Core Lab
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Center
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Division
dc.contributor.departmentCore Labs
dc.contributor.departmentAdvanced Nanofabrication, Imaging and Characterization Core Lab
dc.identifier.journalPhosphorus, Sulfur, and Silicon and the Related Elements
dc.contributor.institutionDepartment of Applied Chemistry, Faculty of Applied Sciences, Taibah University, Madinah 1343, Saudi Arabia
kaust.personEmwas, Abdul-Hamid M.
kaust.personAl-Talla, Zeyad
kaust.personAl Kordi, Mohamed
dc.relation.isSupplementedByAl-Masri, H. T., Emwas, A.-H. M., Al-Talla, Z. A., & Alkordi, M. H. (2012). CCDC 844302: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccxbkkb
dc.relation.isSupplementedByDOI:10.5517/ccxbkkb
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624658
dc.relation.isSupplementedByAl-Masri, H. T., Emwas, A.-H. M., Al-Talla, Z. A., & Alkordi, M. H. (2012). CCDC 844303: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccxbklc
dc.relation.isSupplementedByDOI:10.5517/ccxbklc
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624659


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