Post-synthetic modification of porphyrin-encapsulating metal-organic materials by cooperative addition of inorganic salts to enhance CO 2/CH 4 selectivity

Type
Article
Authors
Zhang, Zhenjie
Gao, Wenyang
Wojtas, Łukasz
Ma, Shengqian
Eddaoudi, Mohamed cc
Zaworotko, Michael J.
KAUST Department
Advanced Membranes and Porous Materials Research Center
Biological and Environmental Sciences and Engineering (BESE) Division
Chemical Science Program
Functional Materials Design, Discovery and Development (FMD3)
Physical Science and Engineering (PSE) Division
Date
2012-08-21
Online Publication Date
2012-08-21
Print Publication Date
2012-09-10
Permanent link to this record
http://hdl.handle.net/10754/562279

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Abstract
Keeping MOM: Reaction of biphenyl-3,4',5-tricarboxylate and Cd(NO 3) 2 in the presence of meso-tetra(N-methyl-4-pyridyl) porphine tetratosylate afforded porph@MOM-11, a microporous metal-organic material (MOM) that encapsulates cationic porphyrins and solvent in alternating open channels. Porph@MOM-11 has cation and anion binding sites that facilitate cooperative addition of inorganic salts (such as M +Cl -) in a stoichiometric fashion. © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Sponsors
This work is supported by King Abdullah University of Science and Technology (FIC/2010/06). The microcrystal diffraction of porph(Cl<SUP>-</SUP>)@MOM-11(Mn<SUP>2+</SUP>) was carried at the Advanced Photon Source on beamline 15ID-B at ChemMatCARS Sector 15 (NSF/CHE-0822838 and DE-AC02-06CH11357).
Publisher
Wiley
Journal
Angewandte Chemie International Edition
DOI
10.1002/anie.201203594
Relations
Is Supplemented By:
  • [Dataset]
    Zhang, Z., Gao, W.-Y., Wojtas, L., Ma, S., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 878570: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyh6zl. DOI: 10.5517/ccyh6zl HANDLE: 10754/624700
  • [Dataset]
    Zhang, Z., Gao, W.-Y., Wojtas, L., Ma, S., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 878571: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyh70n. DOI: 10.5517/ccyh70n HANDLE: 10754/624701
  • [Dataset]
    Zhang, Z., Gao, W.-Y., Wojtas, L., Ma, S., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 878572: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyh71p. DOI: 10.5517/ccyh71p HANDLE: 10754/624702
  • [Dataset]
    Zhang, Z., Gao, W.-Y., Wojtas, L., Ma, S., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 878573: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyh72q. DOI: 10.5517/ccyh72q HANDLE: 10754/624703
  • [Dataset]
    Zhang, Z., Gao, W.-Y., Wojtas, L., Ma, S., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 878574: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyh73r. DOI: 10.5517/ccyh73r HANDLE: 10754/624704
Collections
Articles; Biological and Environmental Sciences and Engineering (BESE) Division; Advanced Membranes and Porous Materials Research Center; Physical Science and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3); Chemical Science Program