Post-synthetic modification of porphyrin-encapsulating metal-organic materials by cooperative addition of inorganic salts to enhance CO 2/CH 4 selectivity
Type
ArticleAuthors
Zhang, ZhenjieGao, Wenyang
Wojtas, Łukasz
Ma, Shengqian
Eddaoudi, Mohamed

Zaworotko, Michael J.
KAUST Department
Advanced Membranes and Porous Materials Research CenterBiological and Environmental Sciences and Engineering (BESE) Division
Chemical Science Program
Functional Materials Design, Discovery and Development (FMD3)
Physical Science and Engineering (PSE) Division
Date
2012-08-21Online Publication Date
2012-08-21Print Publication Date
2012-09-10Permanent link to this record
http://hdl.handle.net/10754/562279
Metadata
Show full item recordAbstract
Keeping MOM: Reaction of biphenyl-3,4',5-tricarboxylate and Cd(NO 3) 2 in the presence of meso-tetra(N-methyl-4-pyridyl) porphine tetratosylate afforded porph@MOM-11, a microporous metal-organic material (MOM) that encapsulates cationic porphyrins and solvent in alternating open channels. Porph@MOM-11 has cation and anion binding sites that facilitate cooperative addition of inorganic salts (such as M +Cl -) in a stoichiometric fashion. © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.Citation
Zhang, Z., Gao, W.-Y., Wojtas, L., Ma, S., Eddaoudi, M., & Zaworotko, M. J. (2012). Post-Synthetic Modification of Porphyrin-Encapsulating Metal-Organic Materials by Cooperative Addition of Inorganic Salts to Enhance CO2/CH4Selectivity. Angewandte Chemie International Edition, 51(37), 9330–9334. doi:10.1002/anie.201203594Sponsors
This work is supported by King Abdullah University of Science and Technology (FIC/2010/06). The microcrystal diffraction of porph(Cl<SUP>-</SUP>)@MOM-11(Mn<SUP>2+</SUP>) was carried at the Advanced Photon Source on beamline 15ID-B at ChemMatCARS Sector 15 (NSF/CHE-0822838 and DE-AC02-06CH11357).Publisher
WileyJournal
Angewandte ChemieRelations
Is Supplemented By:- [Dataset]
Zhang, Z., Gao, W.-Y., Wojtas, L., Ma, S., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 878570: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyh6zl. DOI: 10.5517/ccyh6zl HANDLE: 10754/624700 - [Dataset]
Zhang, Z., Gao, W.-Y., Wojtas, L., Ma, S., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 878571: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyh70n. DOI: 10.5517/ccyh70n HANDLE: 10754/624701 - [Dataset]
Zhang, Z., Gao, W.-Y., Wojtas, L., Ma, S., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 878572: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyh71p. DOI: 10.5517/ccyh71p HANDLE: 10754/624702 - [Dataset]
Zhang, Z., Gao, W.-Y., Wojtas, L., Ma, S., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 878573: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyh72q. DOI: 10.5517/ccyh72q HANDLE: 10754/624703 - [Dataset]
Zhang, Z., Gao, W.-Y., Wojtas, L., Ma, S., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 878574: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyh73r. DOI: 10.5517/ccyh73r HANDLE: 10754/624704
ae974a485f413a2113503eed53cd6c53
10.1002/anie.201203594