Post-synthetic modification of porphyrin-encapsulating metal-organic materials by cooperative addition of inorganic salts to enhance CO 2/CH 4 selectivity

Type
Article
Authors
Zhang, ZhenJie
Gao, Wenyang
Wojtas, Łukasz
Ma, Shengqian
Eddaoudi, Mohamed cc
Zaworotko, Michael J.
KAUST Department
Chemical Science Program
Physical Sciences and Engineering (PSE) Division
Advanced Membranes and Porous Materials Research Center
Functional Materials Design, Discovery and Development (FMD3)
Date
2012-08-21

Metadata
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Abstract
Keeping MOM: Reaction of biphenyl-3,4',5-tricarboxylate and Cd(NO 3) 2 in the presence of meso-tetra(N-methyl-4-pyridyl) porphine tetratosylate afforded porph@MOM-11, a microporous metal-organic material (MOM) that encapsulates cationic porphyrins and solvent in alternating open channels. Porph@MOM-11 has cation and anion binding sites that facilitate cooperative addition of inorganic salts (such as M +Cl -) in a stoichiometric fashion. © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Sponsors
This work is supported by King Abdullah University of Science and Technology (FIC/2010/06). The microcrystal diffraction of porph(Cl<SUP>-</SUP>)@MOM-11(Mn<SUP>2+</SUP>) was carried at the Advanced Photon Source on beamline 15ID-B at ChemMatCARS Sector 15 (NSF/CHE-0822838 and DE-AC02-06CH11357).
Publisher
Wiley-Blackwell
Journal
Angewandte Chemie International Edition
ISSN
14337851
DOI
10.1002/anie.201203594
Handle URI
http://hdl.handle.net/10754/562279
Is Supplemented By
Zhang, Z., Gao, W.-Y., Wojtas, L., Ma, S., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 878570: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyh6zl
DOI:10.5517/ccyh6zl
HANDLE:http://hdl.handle.net/10754/624700
Zhang, Z., Gao, W.-Y., Wojtas, L., Ma, S., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 878571: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyh70n
DOI:10.5517/ccyh70n
HANDLE:http://hdl.handle.net/10754/624701
Zhang, Z., Gao, W.-Y., Wojtas, L., Ma, S., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 878572: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyh71p
DOI:10.5517/ccyh71p
HANDLE:http://hdl.handle.net/10754/624702
Zhang, Z., Gao, W.-Y., Wojtas, L., Ma, S., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 878573: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyh72q
DOI:10.5517/ccyh72q
HANDLE:http://hdl.handle.net/10754/624703
Zhang, Z., Gao, W.-Y., Wojtas, L., Ma, S., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 878574: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyh73r
DOI:10.5517/ccyh73r
HANDLE:http://hdl.handle.net/10754/624704
Collections
Articles; Advanced Membranes and Porous Materials Research Center; Physical Sciences and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3); Chemical Science Program