Ruthenium(II) pincer complexes with oxazoline arms for efficient transfer hydrogenation reactions
KAUST DepartmentBiological and Environmental Sciences and Engineering (BESE) Division
KAUST Catalysis Center (KCC)
Physical Sciences and Engineering (PSE) Division
Chemical Science Program
Biological & Organometallic Catalysis Laboratories
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AbstractWell-defined P NN CN pincer ruthenium complexes bearing both strong phosphine and weak oxazoline donors were developed. These easily accessible complexes exhibit significantly better catalytic activity in transfer hydrogenation of ketones compared to their PN 3P analogs. These reactions proceed under mild and base-free conditions via protonation- deprotonation of the 'NH' group in the aromatization-dearomatization process. © 2012 Elsevier Ltd. All rights reserved.
SponsorsWe are grateful for the generous financial support from the King Abdullah University of Science and Technology.
Is Supplemented ByChen, T., He, L.-P., Gong, D., Yang, L., Miao, X., Eppinger, J., & Huang, K.-W. (2012). CCDC 885734: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyqp2d