Homocoupling of benzyl halides catalyzed by POCOP-nickel pincer complexes
Type
ArticleAuthors
Chen, TaoYang, Limin
LI, LIANG
Huang, Kuo-Wei
KAUST Department
Advanced Nanofabrication, Imaging and Characterization Core LabBiological and Environmental Sciences and Engineering (BESE) Division
Chemical Science Program
Core Labs
Homogeneous Catalysis Laboratory (HCL)
Imaging and Characterization Core Lab
KAUST Catalysis Center (KCC)
Physical Science and Engineering (PSE) Division
Date
2012-08Abstract
Two types of POCOP-nickel(II) pincer complexes were prepared by mixing POCOP pincer ligands and NiX 2 in toluene at reflux. The resulting nickel complexes efficiently catalyze the homocoupling reactions of benzyl halides in the presence of zinc. The coupled products were obtained in excellent to quantitative yields. © 2012 Elsevier Ltd. All rights reserved.Citation
Chen, T., Yang, L., Li, L., & Huang, K.-W. (2012). Homocoupling of benzyl halides catalyzed by POCOP–nickel pincer complexes. Tetrahedron, 68(31), 6152–6157. doi:10.1016/j.tet.2012.05.075Acknowledgements
We are grateful for the generous financial support from King Abdullah University of Science and Technology.Publisher
Elsevier BVJournal
TetrahedronDOI
10.1016/j.tet.2012.05.075Relations
Is Supplemented By:- [Dataset]
Chen, T., Yang, L., Li, L., & Huang, K.-W. (2012). CCDC 879684: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyjcxq. DOI: 10.5517/ccyjcxq HANDLE: 10754/624711 - [Dataset]
Chen, T., Yang, L., Li, L., & Huang, K.-W. (2012). CCDC 879685: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyjcyr. DOI: 10.5517/ccyjcyr HANDLE: 10754/624712 - [Dataset]
Chen, T., Yang, L., Li, L., & Huang, K.-W. (2012). CCDC 879686: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyjczs. DOI: 10.5517/ccyjczs HANDLE: 10754/624713