Synthesis and gas transport properties of hydroxyl-functionalized polyimides with intrinsic microporosity
KAUST DepartmentAdvanced Membranes and Porous Materials Research Center
Biological and Environmental Sciences and Engineering (BESE) Division
Physical Sciences and Engineering (PSE) Division
Chemical and Biological Engineering Program
Chemical Science Program
Nanostructured Functional Materials (NFM) laboratory
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AbstractA newly designed diamine monomer, 3,3,3′,3′-tetramethyl-1, 1′-spirobisindane-5,5′-diamino-6,6′-diol, was successfully used to synthesize two types of polyimides for membrane-based gas separation applications. The novel polymers integrate significant microporosity and polar hydroxyl groups, showing the combined features of polymers of intrinsic microporosity (PIMs) and functional polyimides (PIs). They possess high thermal stability, good solubility, and easy processability for membrane fabrication; the resulting membranes exhibit good permeability owing to the intrinsic microporosity introduced by the highly contorted PIM segments as well as high CO 2/CH 4 selectivity that arises from the hydroxyl groups. The membranes show CO 2/CH 4 selectivities of >20 when tested with a 1:1 CO 2/CH 4 mixture for feed pressures up to 50 bar. In addition, the incorporation of hydroxyl groups and microporosity in the polymers enhances their affinity to water, leading to remarkable water sorption capacities of up to 22 wt % at 35 °C and 95% relative humidity. © 2012 American Chemical Society.
SponsorsThis research was supported by KAUST baseline funding for Yu Han and Ingo Pinnau.
PublisherAmerican Chemical Society (ACS)
Is Supplemented ByMa, X., Swaidan, R., Belmabkhout, Y., Zhu, Y., Litwiller, E., Jouiad, M., … Han, Y. (2013). CCDC 838941: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccx4zmm