[PdA (IPr*) (cinnamyl)Cl]: An efficient pre-catalyst for the preparation of tetra-ortho-substituted biaryls by Suzuki-Miyaura cross-coupling
dc.contributor.author | Chartoire, Anthony | |
dc.contributor.author | Lesieur, Mathieu | |
dc.contributor.author | Falivene, Laura | |
dc.contributor.author | Slawin, Alexandra M. Z. | |
dc.contributor.author | Cavallo, Luigi | |
dc.contributor.author | Cazin, Catherine S. J. | |
dc.contributor.author | Nolan, Steven P. | |
dc.date.accessioned | 2015-08-03T09:45:26Z | |
dc.date.available | 2015-08-03T09:45:26Z | |
dc.date.issued | 2012-03-13 | |
dc.identifier.issn | 09476539 | |
dc.identifier.doi | 10.1002/chem.201104009 | |
dc.identifier.uri | http://hdl.handle.net/10754/562127 | |
dc.description.abstract | The bigger the better: The new well-defined [Pd(IPr*)(cin)Cl] pre-catalyst is described (see scheme). This complex proves to be highly active in the Suzuki-Miyaura cross-coupling for the synthesis of tetra-ortho- substituted biaryls under mild conditions. IPr* is reported as the largest N-heterocyclic carbene (NHC) to date for [Pd(NHC)(cin)Cl] complexes, explaining the high reactivity observed for this complex in this challenging transformation. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. | |
dc.description.sponsorship | We gratefully acknowledge the EC for funding through the seventh framework programme SYNFLOW. We thank the EPSCR National Mass Spectrometry Service Center in Swansea for mass spectrometric analyses. Umicore AG is thanked for its generous gifts of materials. S.P.N. is a Royal Society Wolfson Research Merit Award holder. C.S.J.C. acknowledges the Royal Society for a University Research Fellowship. | |
dc.publisher | Wiley | |
dc.subject | biaryls | |
dc.subject | cross-coupling | |
dc.subject | N-heterocyclic carbenes | |
dc.subject | palladium | |
dc.title | [PdA (IPr*) (cinnamyl)Cl]: An efficient pre-catalyst for the preparation of tetra-ortho-substituted biaryls by Suzuki-Miyaura cross-coupling | |
dc.type | Article | |
dc.contributor.department | Biological and Environmental Sciences and Engineering (BESE) Division | |
dc.contributor.department | Chemical Science Program | |
dc.contributor.department | KAUST Catalysis Center (KCC) | |
dc.contributor.department | Physical Science and Engineering (PSE) Division | |
dc.identifier.journal | Chemistry - A European Journal | |
dc.contributor.institution | EaStCHEM School of Chemistry, University of St Andrews, St Andrews, KY16 9ST, United Kingdom | |
dc.contributor.institution | Dipartimento di Chimica, Università di Salerno, Via Ponte don Melillo, 84084 Fisciano, Italy | |
kaust.person | Cavallo, Luigi | |
dc.relation.issupplementedby | DOI:10.5517/ccxsr8p | |
display.relations | <b> Is Supplemented By:</b> <br/> <ul><li><i>[Dataset]</i> <br/> Chartoire, A., Lesieur, M., Falivene, L., Slawin, A. M. Z., Cavallo, L., Cazin, C. S. J., & Nolan, S. P. (2012). CCDC 857933: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccxsr8p. DOI: <a href="https://doi.org/10.5517/ccxsr8p">10.5517/ccxsr8p</a> HANDLE: <a href="http://hdl.handle.net/10754/624668">10754/624668</a></li></ul> | |
dc.date.published-online | 2012-03-13 | |
dc.date.published-print | 2012-04-10 |
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