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    [PdA (IPr*) (cinnamyl)Cl]: An efficient pre-catalyst for the preparation of tetra-ortho-substituted biaryls by Suzuki-Miyaura cross-coupling

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    Type
    Article
    Authors
    Chartoire, Anthony
    Lesieur, Mathieu
    Falivene, Laura cc
    Slawin, Alexandra M. Z.
    Cavallo, Luigi cc
    Cazin, Catherine S. J. cc
    Nolan, Steven P. cc
    KAUST Department
    Biological and Environmental Sciences and Engineering (BESE) Division
    Chemical Science Program
    KAUST Catalysis Center (KCC)
    Physical Science and Engineering (PSE) Division
    Date
    2012-03-13
    Online Publication Date
    2012-03-13
    Print Publication Date
    2012-04-10
    Permanent link to this record
    http://hdl.handle.net/10754/562127
    
    Metadata
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    Abstract
    The bigger the better: The new well-defined [Pd(IPr*)(cin)Cl] pre-catalyst is described (see scheme). This complex proves to be highly active in the Suzuki-Miyaura cross-coupling for the synthesis of tetra-ortho- substituted biaryls under mild conditions. IPr* is reported as the largest N-heterocyclic carbene (NHC) to date for [Pd(NHC)(cin)Cl] complexes, explaining the high reactivity observed for this complex in this challenging transformation. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
    Citation
    Chartoire, A., Lesieur, M., Falivene, L., Slawin, A. M. Z., Cavallo, L., Cazin, C. S. J., & Nolan, S. P. (2012). [Pd(IPr*)(cinnamyl)Cl]: An Efficient Pre-catalyst for the Preparation of Tetra-ortho-substituted Biaryls by Suzuki-Miyaura Cross-Coupling. Chemistry - A European Journal, 18(15), 4517–4521. doi:10.1002/chem.201104009
    Sponsors
    We gratefully acknowledge the EC for funding through the seventh framework programme SYNFLOW. We thank the EPSCR National Mass Spectrometry Service Center in Swansea for mass spectrometric analyses. Umicore AG is thanked for its generous gifts of materials. S.P.N. is a Royal Society Wolfson Research Merit Award holder. C.S.J.C. acknowledges the Royal Society for a University Research Fellowship.
    Publisher
    Wiley
    Journal
    Chemistry - A European Journal
    DOI
    10.1002/chem.201104009
    Relations
    Is Supplemented By:
    • [Dataset]
      Chartoire, A., Lesieur, M., Falivene, L., Slawin, A. M. Z., Cavallo, L., Cazin, C. S. J., & Nolan, S. P. (2012). CCDC 857933: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccxsr8p. DOI: 10.5517/ccxsr8p HANDLE: 10754/624668
    ae974a485f413a2113503eed53cd6c53
    10.1002/chem.201104009
    Scopus Count
    Collections
    Articles; Biological and Environmental Science and Engineering (BESE) Division; Physical Science and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)

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