Blue-emitting dinuclear N-heterocyclic dicarbene gold(I) complex featuring a nearly unit quantum yield
KAUST DepartmentBiological and Environmental Sciences and Engineering (BESE) Division
Chemical Science Program
KAUST Catalysis Center (KCC)
Physical Science and Engineering (PSE) Division
Online Publication Date2012-01-23
Print Publication Date2012-02-06
Permanent link to this recordhttp://hdl.handle.net/10754/562086
MetadataShow full item record
AbstractDinuclear N-heterocyclic dicarbene gold(I) complexes of general formula [Au 2(RIm-Y-ImR) 2](PF 6) 2 (R = Me, Cy; Y = (CH 2) 1-4, o-xylylene, m-xylylene) have been synthesized and screened for their luminescence properties. All the complexes are weakly emissive in solution whereas in the solid state some of them show significant luminescence intensities. In particular, crystals or powders of the complex with R = Me, Y = (CH 2) 3 exhibit an intense blue emission (λ max = 450 nm) with a high quantum yield (Φ em = 0.96). The X-ray crystal structure of this complex is characterized by a rather short intramolecular Au•••Au distance (3.272 Ǻ). Time dependent density functional theory (TDDFT) calculations have been used to calculate the UV/vis properties of the ground state as well as of the first excited state of the complex, the latter featuring a significantly shorter Au•••Au distance. © 2012 American Chemical Society.
CitationBaron, M., Tubaro, C., Biffis, A., Basato, M., Graiff, C., Poater, A., … Accorsi, G. (2012). Blue-Emitting Dinuclear N-heterocyclic Dicarbene Gold(I) Complex Featuring a Nearly Unit Quantum Yield. Inorganic Chemistry, 51(3), 1778–1784. doi:10.1021/ic2020786
SponsorsC.T. thanks the University of Padova for financial support (CPDA085452 and HELIOS). This work was also supported by EC (ITN "FINELUMEN" PITN-GA-2008-215399) and the CNR (PM.P04.010, MACOL). Dr. Valerio Causin is gratefully acknowledged for the powder XRD measurements.
PublisherAmerican Chemical Society (ACS)
RelationsIs Supplemented By:
Baron, M., Tubaro, C., Biffis, A., Basato, M., Graiff, C., Poater, A., … Accorsi, G. (2012). CCDC 835523: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccx1fcq. DOI: 10.5517/ccx1fcq HANDLE: 10754/624653
Baron, M., Tubaro, C., Biffis, A., Basato, M., Graiff, C., Poater, A., … Accorsi, G. (2012). CCDC 855138: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccxpv3j. DOI: 10.5517/ccxpv3j HANDLE: 10754/624667
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