Template-directed synthesis of nets based upon octahemioctahedral cages that encapsulate catalytically active metalloporphyrins

Zhang, Zhenjie; Zhang, Linping; Wojtas, Łukasz; Eddaoudi, Mohamed; Zaworotko, Michael J.

Type

Article

Date

2011-12-29

Online Publication Date

2011-12-29

Print Publication Date

2012-01-18

Permanent link to this record

http://hdl.handle.net/10754/562061

Metadata

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Abstract

meso-Tetra(N-methyl-4-pyridyl)porphine tetratosylate (TMPyP) templates the synthesis of six new metal-organic materials by the reaction of benzene-1,3,5-tricarboxylate with transition metals, five of which exhibit HKUST-1 or tbo topology (M = Fe, Mn, Co, Ni, Mg). The resulting materials, porph@MOMs, selectively encapsulate the corresponding metalloporphyrins in octahemioctahedral cages and can serve as size-selective heterogeneous catalysts for oxidation of olefins. © 2011 American Chemical Society.

Sponsors

This publication is based on work supported by Award FIC/2010/06 made by King Abdullah University of Science and Technology (KAUST). The data for porph@MOM-5, -6, and -9 were collected at the Advanced Photon Source on beamline 15ID-C of ChemMatCARS Sector 15, which is principally supported by the National Science Foundation and the Department of Energy under Grant NSF/CHE-0822838. The Advanced Photon Source is supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under Contract DE-AC02-06CH11357.

Publisher

American Chemical Society (ACS)

Journal

Journal of the American Chemical Society

DOI

10.1021/ja208256u

Collections

Articles; Biological and Environmental Sciences and Engineering (BESE) Division; Advanced Membranes and Porous Materials Research Center; Physical Sciences and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3); Chemical Science Program