Template-directed synthesis of nets based upon octahemioctahedral cages that encapsulate catalytically active metalloporphyrins
Type
Article
KAUST Department
Advanced Membranes and Porous Materials Research CenterBiological and Environmental Sciences and Engineering (BESE) Division
Chemical Science Program
Functional Materials Design, Discovery and Development (FMD3)
Physical Science and Engineering (PSE) Division
KAUST Grant Number
FIC/2010/06Date
2011-12-29Online Publication Date
2011-12-29Print Publication Date
2012-01-18Permanent link to this record
http://hdl.handle.net/10754/562061Metadata
Show full item recordAbstract
meso-Tetra(N-methyl-4-pyridyl)porphine tetratosylate (TMPyP) templates the synthesis of six new metal-organic materials by the reaction of benzene-1,3,5-tricarboxylate with transition metals, five of which exhibit HKUST-1 or tbo topology (M = Fe, Mn, Co, Ni, Mg). The resulting materials, porph@MOMs, selectively encapsulate the corresponding metalloporphyrins in octahemioctahedral cages and can serve as size-selective heterogeneous catalysts for oxidation of olefins. © 2011 American Chemical Society.Sponsors
This publication is based on work supported by Award FIC/2010/06 made by King Abdullah University of Science and Technology (KAUST). The data for porph@MOM-5, -6, and -9 were collected at the Advanced Photon Source on beamline 15ID-C of ChemMatCARS Sector 15, which is principally supported by the National Science Foundation and the Department of Energy under Grant NSF/CHE-0822838. The Advanced Photon Source is supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under Contract DE-AC02-06CH11357.Publisher
American Chemical Society (ACS)Relations
Is Supplemented By:- [Dataset]
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