Template-directed synthesis of nets based upon octahemioctahedral cages that encapsulate catalytically active metalloporphyrins
Type
Article
KAUST Department
Chemical Science ProgramPhysical Sciences and Engineering (PSE) Division
Advanced Membranes and Porous Materials Research Center
Functional Materials Design, Discovery and Development (FMD3)
Date
2012-01-18Metadata
Show full item recordAbstract
meso-Tetra(N-methyl-4-pyridyl)porphine tetratosylate (TMPyP) templates the synthesis of six new metal-organic materials by the reaction of benzene-1,3,5-tricarboxylate with transition metals, five of which exhibit HKUST-1 or tbo topology (M = Fe, Mn, Co, Ni, Mg). The resulting materials, porph@MOMs, selectively encapsulate the corresponding metalloporphyrins in octahemioctahedral cages and can serve as size-selective heterogeneous catalysts for oxidation of olefins. © 2011 American Chemical Society.Sponsors
This publication is based on work supported by Award FIC/2010/06 made by King Abdullah University of Science and Technology (KAUST). The data for porph@MOM-5, -6, and -9 were collected at the Advanced Photon Source on beamline 15ID-C of ChemMatCARS Sector 15, which is principally supported by the National Science Foundation and the Department of Energy under Grant NSF/CHE-0822838. The Advanced Photon Source is supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under Contract DE-AC02-06CH11357.Publisher
American Chemical Society (ACS)ISSN
00027863Handle URI
http://hdl.handle.net/10754/562061Is Supplemented By
Zhang, Z., Zhang, L., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2012). CCDC 877427: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyg13jDOI:10.5517/ccyg13j
HANDLE:http://hdl.handle.net/10754/624695
Zhang, Z., Zhang, L., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2012). CCDC 877428: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyg14k
DOI:10.5517/ccyg14k
HANDLE:http://hdl.handle.net/10754/624696
Zhang, Z., Zhang, L., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2012). CCDC 877429: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyg15l
DOI:10.5517/ccyg15l
HANDLE:http://hdl.handle.net/10754/624697
Zhang, Z., Zhang, L., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2012). CCDC 877430: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyg16m
DOI:10.5517/ccyg16m
HANDLE:http://hdl.handle.net/10754/624698
Zhang, Z., Zhang, L., Wojtas, L., Eddaoudi, M., & Zaworotko, M. J. (2012). CCDC 877431: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyg17n
DOI:10.5517/ccyg17n
HANDLE:http://hdl.handle.net/10754/624699