Templated synthesis, postsynthetic metal exchange, and properties of a porphyrin-encapsulating metal-organic material
Nugent, Patrick S.
Zaworotko, Michael J.
KAUST DepartmentChemical Science Program
Physical Sciences and Engineering (PSE) Division
Advanced Membranes and Porous Materials Research Center
Functional Materials Design, Discovery and Development (FMD3)
Permanent link to this recordhttp://hdl.handle.net/10754/562060
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AbstractReaction of biphenyl-3,4′,5-tricarboxylate (H 3BPT) and CdCl 2 in the presence of meso-tetra(N-methyl-4-pyridyl)porphine tetratosylate (TMPyP) afforded porph@MOM-10, a microporous metal-organic material containing CdTMPyP cations encapsulated in an anionic Cd(II) carboxylate framework, [Cd 6(BPT) 4Cl 4(H 2O) 4]. Porph@MOM-10 is a versatile platform that undergoes exchange to serve as the parent of a series of porph@MOMs that exhibit permanent porosity and heterogeneous catalytic activity. © 2011 American Chemical Society.
SponsorsThis publication is based on work supported by Award FIC/2010/06 made by King Abdullah University of Science and Technology (KAUST).
PublisherAmerican Chemical Society (ACS)