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dc.contributor.authorYao, Liangfeng
dc.contributor.authorTan, Davin
dc.contributor.authorMiao, Xiaohe
dc.contributor.authorHuang, Kuo-Wei
dc.date.accessioned2015-08-03T09:42:51Z
dc.date.available2015-08-03T09:42:51Z
dc.date.issued2012
dc.identifier.issn20462069
dc.identifier.doi10.1039/c2ra20852k
dc.identifier.urihttp://hdl.handle.net/10754/562014
dc.description.abstractAn efficient method of preparing hydroxylfluorenes by TsOH-mediated tandem alkylation/rearrangements of propargylic alcohols with 1,3-diketones is described. These reactions are accomplished in moderate to good yields under mild conditions to offer a straightforward and convenient one step synthetic route to hydroxylfluorene derivatives through a plausible mechanism involving a sequence of dehydration, addition, rearrangement and aromatization. This journal is © The Royal Society of Chemistry 2012.
dc.description.sponsorshipWe would like to acknowledge the financial support from the King Abdullah University of Science and Technology and the assistance given by the Core Laboratories.
dc.publisherRoyal Society of Chemistry (RSC)
dc.titleA route to hydroxylfluorenes: TsOH-mediated condensation reactions of 1,3-diketones with propargylic alcohols
dc.typeArticle
dc.contributor.departmentBiological and Environmental Sciences and Engineering (BESE) Division
dc.contributor.departmentChemical Science Program
dc.contributor.departmentHomogeneous Catalysis Laboratory (HCL)
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalRSC Advances
kaust.personYao, Liangfeng
kaust.personTan, Davin
kaust.personMiao, Xiaohe
kaust.personHuang, Kuo-Wei
dc.relation.issupplementedbyDOI:10.5517/ccyjc3x
display.relations<b> Is Supplemented By:</b> <br/> <ul><li><i>[Dataset]</i> <br/> Yao, L.-F., Tan, D., Miao, X., & Huang, K.-W. (2012). CCDC 879659: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccyjc3x. DOI: <a href="https://doi.org/10.5517/ccyjc3x">10.5517/ccyjc3x</a> HANDLE: <a href="http://hdl.handle.net/10754/624710">10754/624710</a></li></ul>


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