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Tetrakis(4-tert-butylphenyl) substituted and fused quinoidal porphyrins

dc.contributor.authorZeng, Wangdong
dc.contributor.authorLee, Byungsun
dc.contributor.authorSung, Youngmo
dc.contributor.authorHuang, Kuo-Wei
dc.contributor.authorLi, Yuan
dc.contributor.authorKim, Dongho
dc.contributor.authorWu, Jishan
dc.date.accessioned2015-08-03T09:36:08Z
dc.date.available2015-08-03T09:36:08Z
dc.date.issued2012
dc.identifier.citationZeng, W., Lee, B. S., Sung, Y. M., Huang, K.-W., Li, Y., Kim, D., & Wu, J. (2012). Tetrakis(4-tert-butylphenyl) substituted and fused quinoidal porphyrins. Chemical Communications, 48(62), 7684. doi:10.1039/c2cc33728b
dc.identifier.issn13597345
dc.identifier.doi10.1039/c2cc33728b
dc.identifier.urihttp://hdl.handle.net/10754/562008
dc.description.abstract4-tert-Butylphenyl-substituted and fused quinoidal porphyrins 1 and 2 are prepared for the first time. They show (1) intense one-photon absorption in the far-red/near-infrared region, (2) enhanced two-photon absorption compared with aromatic porphyrin monomers, and (3) amphoteric redox behavior. Their geometry and electronic structure are studied by DFT calculations. This journal is © 2012 The Royal Society of Chemistry.
dc.description.sponsorshipJ. W. acknowledges the financial support from the BMRC-NMRC grant (no. 10/1/21/19/642), MOE Tier 2 grant (MOE2011-T2-2-130) and IMRE Core Funding (IMRE/10-1P0509). The work at Yonsei Univ. was supported by WCU (World Class University) programs (R32-2010-10217-0) and an AFSOR/APARD grant (no. FA2386-09-1-4092). K.-W. H. acknowledges the financial support from KAUST.
dc.publisherRoyal Society of Chemistry (RSC)
dc.titleTetrakis(4-tert-butylphenyl) substituted and fused quinoidal porphyrins
dc.typeArticle
dc.contributor.departmentBiological and Environmental Sciences and Engineering (BESE) Division
dc.contributor.departmentChemical Science Program
dc.contributor.departmentHomogeneous Catalysis Laboratory (HCL)
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalChemical Communications
dc.contributor.institutionDepartment of Chemistry, National University of Singapore, 3 Science Drive 3, 117543 Singapore, Singapore
dc.contributor.institutionSpectroscopy Laboratory for Functional pi-Electronic Systems, Department of Chemistry, Yonsei University, Seoul 120-749, South Korea
dc.contributor.institutionInstitute of Materials Research and Engineering, A Star 3 Research Link, C 117602 Singapore, Singapore
kaust.personHuang, Kuo-Wei


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