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dc.contributor.authorLeitgeb, Anita
dc.contributor.authorAbbas, Mudassar E.
dc.contributor.authorFischer, Roland C.
dc.contributor.authorPoater, Albert
dc.contributor.authorCavallo, Luigi
dc.contributor.authorSlugovc, Christian
dc.date.accessioned2015-08-03T09:36:03Z
dc.date.available2015-08-03T09:36:03Z
dc.date.issued2012
dc.identifier.issn20444753
dc.identifier.doi10.1039/c2cy20311a
dc.identifier.urihttp://hdl.handle.net/10754/562004
dc.description.abstractAn olefin metathesis catalyst featuring a SIPr NHC and an ester chelating carbene ligand is introduced. In contrast to its previously published SIMes analogue, only the trans dichloro configurated isomer was obtained. The two counterparts are tested in various olefin metathesis reactions, revealing a striking superiority of the new complex in the cross metathesis of olefins with methyl vinyl ketone allowing for full conversion with only 500 ppm catalyst loading. © 2012 The Royal Society of Chemistry.
dc.description.sponsorshipFinancial support of this work from the Higher Education Commission of Pakistan (for M. A.) and the European Community (CP-FP 211468-2 EUMET) is gratefully acknowledged. A. P. thanks the Spanish MINECO for a Ramon y Cajal contract (ref. RYC-2009-05226) and the European Commission for a Career Integration Grant (CIG09-GA-2011-293900). The provision of complex M32 by Prof. S. P. Nolan and team (Univ. St. Andrews) is highly appreciated.
dc.publisherRoyal Society of Chemistry (RSC)
dc.titleA latent ruthenium based olefin metathesis catalyst with a sterically demanding NHC ligand
dc.typeArticle
dc.contributor.departmentBiological and Environmental Sciences and Engineering (BESE) Division
dc.contributor.departmentChemical Science Program
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalCatalysis Science & Technology
dc.contributor.institutionGraz University of Technology, Institute for Chemistry and Technology of Materials, Stremayrgasse 9, A 8010 Graz, Austria
dc.contributor.institutionGraz University of Technology, Institute of Inorganic Chemistry, Stremayrgasse 9, A 8010 Graz, Austria
dc.contributor.institutionCatalan Institute for Water Research (ICRA), H2O Building, Scientific and Technological Park of the University of Girona, Emili Grahit 101, E-17003 Girona, Spain
dc.contributor.institutionCampus de Montilivi, Departament de Química, Universitat de Girona, E-17071 Girona, Spain
dc.contributor.institutionDipartimento di Chimica e Biologia, Università di Salerno, Via Ponte don Melillo, 84084, Fisciano, Italy
kaust.personCavallo, Luigi
dc.relation.issupplementedbyDOI:10.5517/ccy29q0
display.relations<b> Is Supplemented By:</b> <br/> <ul><li><i>[Dataset]</i> <br/> Leitgeb, A., Abbas, M., Fischer, R. C., Poater, A., Cavallo, L., & Slugovc, C. (2012). CCDC 866162: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccy29q0. DOI: <a href="https://doi.org/10.5517/ccy29q0">10.5517/ccy29q0</a> HANDLE: <a href="http://hdl.handle.net/10754/624676">10754/624676</a></li></ul>


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