Show simple item record

dc.contributor.authorLattanzi, Alessandra
dc.contributor.authorDe Fusco, Claudia
dc.contributor.authorRusso, Alessio
dc.contributor.authorPoater, Albert
dc.contributor.authorCavallo, Luigi
dc.date.accessioned2015-08-03T09:35:22Z
dc.date.available2015-08-03T09:35:22Z
dc.date.issued2012
dc.identifier.issn13597345
dc.identifier.doi10.1039/c2cc17488j
dc.identifier.urihttp://hdl.handle.net/10754/561973
dc.description.abstractA dramatic enhancement of the diastereo- and enantioselectivity in the nitro-Michael addition reaction organocatalysed by a commercially available α,α-l-diaryl prolinol was disclosed when performing the reaction in unconventional hexafluorobenzene as a medium. DFT calculations were performed to clarify the origin of stereoselectivity and the role of C 6F 6. © The Royal Society of Chemistry 2012.
dc.description.sponsorshipWe thank MIUR for financial support and the Spanish MICINN for a Ramon y Cajal contract (RYC-2009-04170).
dc.publisherRoyal Society of Chemistry (RSC)
dc.titleHexafluorobenzene: A powerful solvent for a noncovalent stereoselective organocatalytic Michael addition reaction
dc.typeArticle
dc.contributor.departmentBiological and Environmental Sciences and Engineering (BESE) Division
dc.contributor.departmentChemical Science Program
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalChem. Commun.
dc.contributor.institutionDipartimento di Chimica e Biologia, Via Ponte don Melillo, 84084, Fisciano, Italy
dc.contributor.institutionCatalan Institute for Water Research (ICRA), H2O Building, Scientific and Technological Park of the University of Girona, Spain
kaust.personCavallo, Luigi


This item appears in the following Collection(s)

Show simple item record