Low temperature hydrogenolysis of waxes to diesel range gasoline and light alkanes: Comparison of catalytic properties of group 4, 5 and 6 metal hydrides supported on silica-alumina
Delgado, Marco L.
De Mallmann, Aimery
Santini, Catherine C.
Szeto, Kaï Chung
KAUST DepartmentChemical Science Program
KAUST Catalysis Center (KCC)
Physical Science and Engineering (PSE) Division
Permanent link to this recordhttp://hdl.handle.net/10754/561971
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AbstractA series of metal hydrides (M = Zr, Hf, Ta, W) supported on silica-alumina were studied for the first time in hydrogenolysis of light alkanes in a continuous flow reactor. It was found that there is a difference in the reaction mechanism between d 0 metal hydrides of group 4 and d 0 ↔ d 2 metal hydrides of group 5 and group 6. Furthermore, the potential application of these catalysts has been demonstrated by the transformation of Fischer-Tropsch wax in a reactive distillation set-up into typical gasoline and diesel molecules in high selectivity (up to 86 wt%). Current results show that the group 4 metal hydrides have a promising yield toward liquid fuels.
CitationNorsic, S., Larabi, C., Delgado, M., Garron, A., de Mallmann, A., Santini, C., … Taoufik, M. (2012). Low temperature hydrogenolysis of waxes to diesel range gasoline and light alkanes: Comparison of catalytic properties of group 4, 5 and 6 metal hydrides supported on silica–alumina. Catal. Sci. Technol., 2(1), 215–219. doi:10.1039/c1cy00256b
SponsorsWe are grateful for the financial support from BP, 150 W Warrenville Road, IL 60563, Naperville, USA.
PublisherRoyal Society of Chemistry (RSC)
JournalCatal. Sci. Technol.