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dc.contributor.authorLi, Baiyan
dc.contributor.authorZhang, Zhijuan
dc.contributor.authorLi, Yi
dc.contributor.authorYao, Kexin
dc.contributor.authorZhu, Yihan
dc.contributor.authorDeng, Zhiyong
dc.contributor.authorYang, Fen
dc.contributor.authorZhou, Xiaojing
dc.contributor.authorLi, Guanghua
dc.contributor.authorWu, Haohan
dc.contributor.authorNijem, Nour
dc.contributor.authorChabal, Yves Jean
dc.contributor.authorLai, Zhiping
dc.contributor.authorHan, Yu
dc.contributor.authorShi, Zhan
dc.contributor.authorFeng, Shouhua
dc.contributor.authorLi, Jing
dc.date.accessioned2015-08-03T09:35:10Z
dc.date.available2015-08-03T09:35:10Z
dc.date.issued2011-12-23
dc.identifier.issn14337851
dc.identifier.doi10.1002/anie.201105966
dc.identifier.urihttp://hdl.handle.net/10754/561964
dc.description.abstractOpen and friendly: The smallest member of the rht-type metal-organic frameworks (MOFs, see picture) constructed by a hexacarboxylate ligand with a nitrogen-rich imino triazine backbone shows a significantly enhanced gas binding affinity relative to all other isoreticular rht-type MOFs. The high adsorption capacity and remarkable selectivity of CO 2 are attributed to the high density of open metal and Lewis basic sites in the framework. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
dc.description.sponsorshipThis work was supported by the Foundation of the National Natural Science Foundation of China (grant numbers 20971054 and 90922034) and the Key Project of the Chinese Ministry of Education. The RU and UTD teams would like to acknowledge support from DOE (grant number DE-FG02-08ER46491). We thank Prof. Xianhe Bu and Dr. Ze Chang (Nankai University, China) and Dr. Ruiping Chen (Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences) for part of the gas adsorption measurements.
dc.publisherWiley-Blackwell
dc.subjectcarbon dioxide capture
dc.subjectgas separation
dc.subjectLewis basic sites
dc.subjectmetal-organic frameworks
dc.subjectopen metal sites
dc.titleEnhanced binding affinity, remarkable selectivity, and high capacity of CO 2 by dual functionalization of a rht-type metal-organic framework
dc.typeArticle
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Center
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Division
dc.contributor.departmentChemical and Biological Engineering Program
dc.contributor.departmentChemical Science Program
dc.contributor.departmentNanostructured Functional Materials (NFM) laboratory
dc.identifier.journalAngewandte Chemie International Edition
dc.contributor.institutionState Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China
dc.contributor.institutionDepartment of Chemistry and Chemical Biology, Rutgers University, 610 Taylor Road, Piscataway, NJ 08854, United States
dc.contributor.institutionDepartment of Materials Science and Engineering, University of Texas at Dallas, Richardson, TX 75080, United States
kaust.personYao, Kexin
kaust.personZhu, Yihan
kaust.personDeng, Zhiyong
kaust.personLai, Zhiping
kaust.personHan, Yu
dc.relation.isSupplementedByLi, B., Zhang, Z., Li, Y., Yao, K., Zhu, Y., Deng, Z., … Li, J. (2012). CCDC 831219: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccwwyj6
dc.relation.isSupplementedByDOI:10.5517/ccwwyj6
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624651


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