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Thiophene-fused tetracene diimide with low band gap and ambipolar behavior

dc.contributor.authorYe, Qun
dc.contributor.authorChang, Jingjing
dc.contributor.authorHuang, Kuo-Wei
dc.contributor.authorChi, Chunyan
dc.date.accessioned2015-08-03T09:34:16Z
dc.date.available2015-08-03T09:34:16Z
dc.date.issued2011-11-18
dc.identifier.issn15237060
dc.identifier.doi10.1021/ol202357f
dc.identifier.urihttp://hdl.handle.net/10754/561926
dc.description.abstractThe first tetracene diimide derivative fused with four thiophene rings, TT-TDI, was synthesized by an FeCl3 mediated oxidative cyclodehydrogenation reaction. TT-TDI exhibited a low band gap of 1.52 eV and amphoteric redox behavior. TT-TDI also showed a liquid crystalline property and ambipolar charge transport in thin film field-effect transistors. © 2011 American Chemical Society.
dc.description.sponsorshipC.C. acknowledges financial support from the National University of Singapore under MOE AcRF FRC Grants R-143-000-444-112 and Start Up Grant R-143-000-486-133. K.-W.H. acknowledges the financial support from KAUST.
dc.publisherAmerican Chemical Society (ACS)
dc.titleThiophene-fused tetracene diimide with low band gap and ambipolar behavior
dc.typeArticle
dc.contributor.departmentBiological and Environmental Sciences and Engineering (BESE) Division
dc.contributor.departmentChemical Science Program
dc.contributor.departmentHomogeneous Catalysis Laboratory (HCL)
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalOrganic Letters
dc.contributor.institutionDepartment of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore, 117543, Singapore
kaust.personHuang, Kuo-Wei


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