Thiophene-fused tetracene diimide with low band gap and ambipolar behavior
KAUST DepartmentBiological and Environmental Sciences and Engineering (BESE) Division
Chemical Science Program
Homogeneous Catalysis Laboratory (HCL)
KAUST Catalysis Center (KCC)
Physical Sciences and Engineering (PSE) Division
Permanent link to this recordhttp://hdl.handle.net/10754/561926
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AbstractThe first tetracene diimide derivative fused with four thiophene rings, TT-TDI, was synthesized by an FeCl3 mediated oxidative cyclodehydrogenation reaction. TT-TDI exhibited a low band gap of 1.52 eV and amphoteric redox behavior. TT-TDI also showed a liquid crystalline property and ambipolar charge transport in thin film field-effect transistors. © 2011 American Chemical Society.
SponsorsC.C. acknowledges financial support from the National University of Singapore under MOE AcRF FRC Grants R-143-000-444-112 and Start Up Grant R-143-000-486-133. K.-W.H. acknowledges the financial support from KAUST.
PublisherAmerican Chemical Society (ACS)