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    Thiophene-fused tetracene diimide with low band gap and ambipolar behavior

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    Type
    Article
    Authors
    Ye, Qun
    Chang, Jingjing
    Huang, Kuo-Wei cc
    Chi, Chunyan
    KAUST Department
    Biological and Environmental Sciences and Engineering (BESE) Division
    Chemical Science Program
    Homogeneous Catalysis Laboratory (HCL)
    KAUST Catalysis Center (KCC)
    Physical Science and Engineering (PSE) Division
    Date
    2011-11-18
    Permanent link to this record
    http://hdl.handle.net/10754/561926
    
    Metadata
    Show full item record
    Abstract
    The first tetracene diimide derivative fused with four thiophene rings, TT-TDI, was synthesized by an FeCl3 mediated oxidative cyclodehydrogenation reaction. TT-TDI exhibited a low band gap of 1.52 eV and amphoteric redox behavior. TT-TDI also showed a liquid crystalline property and ambipolar charge transport in thin film field-effect transistors. © 2011 American Chemical Society.
    Citation
    Ye, Q., Chang, J., Huang, K.-W., & Chi, C. (2011). Thiophene-Fused Tetracene Diimide with Low Band Gap and Ambipolar Behavior. Organic Letters, 13(22), 5960–5963. doi:10.1021/ol202357f
    Sponsors
    C.C. acknowledges financial support from the National University of Singapore under MOE AcRF FRC Grants R-143-000-444-112 and Start Up Grant R-143-000-486-133. K.-W.H. acknowledges the financial support from KAUST.
    Publisher
    American Chemical Society (ACS)
    Journal
    Organic Letters
    DOI
    10.1021/ol202357f
    ae974a485f413a2113503eed53cd6c53
    10.1021/ol202357f
    Scopus Count
    Collections
    Articles; Biological and Environmental Science and Engineering (BESE) Division; Physical Science and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)

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