Anthracene-fused BODIPYs as near-infrared dyes with high photostability
KAUST DepartmentBiological and Environmental Sciences and Engineering (BESE) Division
Chemical Science Program
Homogeneous Catalysis Laboratory (HCL)
KAUST Catalysis Center (KCC)
Physical Science and Engineering (PSE) Division
Permanent link to this recordhttp://hdl.handle.net/10754/561925
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AbstractAn anthracene unit was successfully fused to the zigzag edge of a boron dipyrromethene (BODIPY) core by an FeCl 3-mediated oxidative cyclodehydrogenation reaction. Meanwhile, a dimer was also formed by both intramolecular cyclization and intermolecular coupling. The anthracene-fused BODIPY monomer 7a and dimer 7b showed small energy gaps (∼1.4 eV) and near-infrared absorption/emission. Moreover, they exhibited high photostability. © 2011 American Chemical Society.
CitationZeng, L., Jiao, C., Huang, X., Huang, K.-W., Chin, W.-S., & Wu, J. (2011). Anthracene-Fused BODIPYs as Near-Infrared Dyes with High Photostability. Organic Letters, 13(22), 6026–6029. doi:10.1021/ol202493c
SponsorsJ.W. acknowledges financial support from the Singapore DSTA DIRP Project (DSTANUS-DIRP/2008/03), an NRF Competitive Research Program (R-143-000-360-281), and an A*Star BMRC grant (no. 10/1/21/19/642). K.-W.H. acknowledges financial support from KAUST.
PublisherAmerican Chemical Society (ACS)
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