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Network diversity through decoration of trigonal-prismatic nodes: Two-step crystal engineering of cationic metal-organic materials

dc.contributor.authorSchoedel, Alexander
dc.contributor.authorWojtas, Łukasz
dc.contributor.authorKelley, Stephen P.
dc.contributor.authorRogers, Robin D.
dc.contributor.authorEddaoudi, Mohamed
dc.contributor.authorZaworotko, Michael J.
dc.date.accessioned2015-08-03T09:33:35Z
dc.date.available2015-08-03T09:33:35Z
dc.date.issued2011-10-05
dc.identifier.issn14337851
dc.identifier.doi10.1002/anie.201104688
dc.identifier.urihttp://hdl.handle.net/10754/561897
dc.description.abstractMOMs the word! In a two-step process, first a trigonal-prismatic Primary Molecular Building Block ([Cr3O(isonic)6]+, tp-PMBB-1) was formed and then it was connected to linear linkers or square-planar nodes to afford three novel highly charged cationic metal-organic materials (MOMs) with snx, snw, and stp topologies. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
dc.description.sponsorshipThis work is supported by Award No. FIC/2010/06, made by the King Abdullah University of Science and Technology (KAUST). We thank Dr. T. T. Ong and Dr. J. A. Perman for the help in sample characterization and S. Elsaidi for fruitful discussions.
dc.publisherWiley-Blackwell
dc.subjectchromium
dc.subjectcrystal engineering
dc.subjectmesoporous materials
dc.subjectmetal-organic frameworks
dc.subjectsynthesis design
dc.titleNetwork diversity through decoration of trigonal-prismatic nodes: Two-step crystal engineering of cationic metal-organic materials
dc.typeArticle
dc.contributor.departmentChemical Science Program
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Division
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Center
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)
dc.identifier.journalAngewandte Chemie International Edition
dc.contributor.institutionDepartment of Chemistry, University of South Florida, 4202 East Fowler Ave., SCA400, Tampa, FL 33620, United States
dc.contributor.institutionDepartment of Chemistry, Box 870336, University of Alabama Tuscaloosa, 250 Hackberry Lane, Tuscaloosa, AL 35487, United States
kaust.personEddaoudi, Mohamed
dc.relation.isSupplementedBySchoedel, A., Wojtas, L., Kelley, S. P., Rogers, R. D., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 948058: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc10tjjw
dc.relation.isSupplementedByDOI:10.5517/cc10tjjw
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624236
dc.relation.isSupplementedBySchoedel, A., Wojtas, L., Kelley, S. P., Rogers, R. D., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 948059: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc10tjkx
dc.relation.isSupplementedByDOI:10.5517/cc10tjkx
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624237
dc.relation.isSupplementedBySchoedel, A., Wojtas, L., Kelley, S. P., Rogers, R. D., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 948060: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc10tjly
dc.relation.isSupplementedByDOI:10.5517/cc10tjly
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624238
dc.relation.isSupplementedBySchoedel, A., Wojtas, L., Kelley, S. P., Rogers, R. D., Eddaoudi, M., & Zaworotko, M. J. (2013). CCDC 948061: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc10tjmz
dc.relation.isSupplementedByDOI:10.5517/cc10tjmz
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624239


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