Network diversity through decoration of trigonal-prismatic nodes: Two-step crystal engineering of cationic metal-organic materials
Kelley, Stephen P.
Rogers, Robin D.
Zaworotko, Michael J.
KAUST DepartmentChemical Science Program
Physical Sciences and Engineering (PSE) Division
Advanced Membranes and Porous Materials Research Center
Functional Materials Design, Discovery and Development (FMD3)
Permanent link to this recordhttp://hdl.handle.net/10754/561897
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AbstractMOMs the word! In a two-step process, first a trigonal-prismatic Primary Molecular Building Block ([Cr3O(isonic)6]+, tp-PMBB-1) was formed and then it was connected to linear linkers or square-planar nodes to afford three novel highly charged cationic metal-organic materials (MOMs) with snx, snw, and stp topologies. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
SponsorsThis work is supported by Award No. FIC/2010/06, made by the King Abdullah University of Science and Technology (KAUST). We thank Dr. T. T. Ong and Dr. J. A. Perman for the help in sample characterization and S. Elsaidi for fruitful discussions.