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dc.contributor.authorEubank, Jarrod F.
dc.contributor.authorMouttaki, Hasnaa
dc.contributor.authorCairns, Amy
dc.contributor.authorBelmabkhout, Youssef
dc.contributor.authorWojtas, Łukasz
dc.contributor.authorLuebke, Ryan
dc.contributor.authorAl Kordi, Mohamed
dc.contributor.authorEddaoudi, Mohamed
dc.date.accessioned2015-08-03T09:33:02Z
dc.date.available2015-08-03T09:33:02Z
dc.date.issued2011-09-14
dc.identifier.issn00027863
dc.identifier.doi10.1021/ja205658j
dc.identifier.urihttp://hdl.handle.net/10754/561875
dc.description.abstractA new blueprint network for the design and synthesis of porous, functional 3D metal-organic frameworks (MOFs) has been identified, namely, the tbo net. Accordingly, tbo-MOFs based on this unique (3,4)-connected net can be exclusively constructed utilizing a combination of well-known and readily targeted [M(R-BDC)]n MOF layers [i.e., supermolecular building layers (SBLs)] based on the edge-transitive 4,4 square lattice (sql) (i.e., 2D four-building units) and a novel pillaring strategy based on four proximal isophthalate ligands from neighboring SBL membered rings (i.e., two pairs from each layer) covalently cross-linked through an organic quadrangular core (e.g., tetrasubstituted benzene). Our strategy permits the rational design and synthesis of isoreticular structures, functionalized and/or expanded, that possess extra-large nanocapsule-like cages, high porosity, and potential for gas separation and storage, among others. Thus, tbo-MOF serves as an archetypal tunable, isoreticular MOF platform for targeting desired applications. © 2011 American Chemical Society.
dc.description.sponsorshipThis work is dedicated to the memory of I. Dale Shellhammer (1924-2010). The authors gratefully acknowledge funds from NSF (DMR 0548117) and KAUST as well as beamline 151D-C of ChemMatCARS Sector 15 at APS, ANL (DOE DE-AC02-06CH11357, NSF CHE-0822838).
dc.publisherAmerican Chemical Society (ACS)
dc.titleThe quest for modular nanocages: Tbo -MOF as an archetype for mutual substitution, functionalization, and expansion of quadrangular pillar building blocks
dc.typeArticle
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Center
dc.contributor.departmentBiological and Environmental Sciences and Engineering (BESE) Division
dc.contributor.departmentChemical Science Program
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)
dc.contributor.departmentPhysical Sciences and Engineering (PSE) Division
dc.identifier.journalJournal of the American Chemical Society
dc.contributor.institutionDepartment of Chemistry, University of South Florida, 4202 East Fowler Avenue (CHE 205), Tampa, FL 33620, United States
kaust.personCairns, Amy
kaust.personBelmabkhout, Youssef
kaust.personLuebke, Ryan
kaust.personEddaoudi, Mohamed
kaust.personAl Kordi, Mohamed
dc.relation.isSupplementedByEubank, J. F., Mouttaki, H., Cairns, A. J., Belmabkhout, Y., Wojtas, L., Luebke, R., … Eddaoudi, M. (2012). CCDC 855129: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccxptt6
dc.relation.isSupplementedByDOI:10.5517/ccxptt6
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624665
dc.relation.isSupplementedByEubank, J. F., Mouttaki, H., Cairns, A. J., Belmabkhout, Y., Wojtas, L., Luebke, R., … Eddaoudi, M. (2012). CCDC 855128: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccxpts5
dc.relation.isSupplementedByDOI:10.5517/ccxpts5
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624664
dc.relation.isSupplementedByEubank, J. F., Mouttaki, H., Cairns, A. J., Belmabkhout, Y., Wojtas, L., Luebke, R., … Eddaoudi, M. (2012). CCDC 855130: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccxptv7
dc.relation.isSupplementedByDOI:10.5517/ccxptv7
dc.relation.isSupplementedByHANDLE:http://hdl.handle.net/10754/624666


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