The quest for modular nanocages: Tbo -MOF as an archetype for mutual substitution, functionalization, and expansion of quadrangular pillar building blocks
dc.contributor.author | Eubank, Jarrod F. | |
dc.contributor.author | Mouttaki, Hasnaa | |
dc.contributor.author | Cairns, Amy | |
dc.contributor.author | Belmabkhout, Youssef | |
dc.contributor.author | Wojtas, Łukasz | |
dc.contributor.author | Luebke, Ryan | |
dc.contributor.author | Al Kordi, Mohamed | |
dc.contributor.author | Eddaoudi, Mohamed | |
dc.date.accessioned | 2015-08-03T09:33:02Z | |
dc.date.available | 2015-08-03T09:33:02Z | |
dc.date.issued | 2011-09-14 | |
dc.identifier.citation | Eubank, J. F., Mouttaki, H., Cairns, A. J., Belmabkhout, Y., Wojtas, L., Luebke, R., … Eddaoudi, M. (2011). The Quest for Modular Nanocages:tbo-MOF as an Archetype for Mutual Substitution, Functionalization, and Expansion of Quadrangular Pillar Building Blocks. Journal of the American Chemical Society, 133(36), 14204–14207. doi:10.1021/ja205658j | |
dc.identifier.issn | 00027863 | |
dc.identifier.doi | 10.1021/ja205658j | |
dc.identifier.uri | http://hdl.handle.net/10754/561875 | |
dc.description.abstract | A new blueprint network for the design and synthesis of porous, functional 3D metal-organic frameworks (MOFs) has been identified, namely, the tbo net. Accordingly, tbo-MOFs based on this unique (3,4)-connected net can be exclusively constructed utilizing a combination of well-known and readily targeted [M(R-BDC)]n MOF layers [i.e., supermolecular building layers (SBLs)] based on the edge-transitive 4,4 square lattice (sql) (i.e., 2D four-building units) and a novel pillaring strategy based on four proximal isophthalate ligands from neighboring SBL membered rings (i.e., two pairs from each layer) covalently cross-linked through an organic quadrangular core (e.g., tetrasubstituted benzene). Our strategy permits the rational design and synthesis of isoreticular structures, functionalized and/or expanded, that possess extra-large nanocapsule-like cages, high porosity, and potential for gas separation and storage, among others. Thus, tbo-MOF serves as an archetypal tunable, isoreticular MOF platform for targeting desired applications. © 2011 American Chemical Society. | |
dc.description.sponsorship | This work is dedicated to the memory of I. Dale Shellhammer (1924-2010). The authors gratefully acknowledge funds from NSF (DMR 0548117) and KAUST as well as beamline 151D-C of ChemMatCARS Sector 15 at APS, ANL (DOE DE-AC02-06CH11357, NSF CHE-0822838). | |
dc.publisher | American Chemical Society (ACS) | |
dc.title | The quest for modular nanocages: Tbo -MOF as an archetype for mutual substitution, functionalization, and expansion of quadrangular pillar building blocks | |
dc.type | Article | |
dc.contributor.department | Advanced Membranes and Porous Materials Research Center | |
dc.contributor.department | Biological and Environmental Sciences and Engineering (BESE) Division | |
dc.contributor.department | Chemical Science Program | |
dc.contributor.department | Functional Materials Design, Discovery and Development (FMD3) | |
dc.contributor.department | Physical Science and Engineering (PSE) Division | |
dc.identifier.journal | Journal of the American Chemical Society | |
dc.contributor.institution | Department of Chemistry, University of South Florida, 4202 East Fowler Avenue (CHE 205), Tampa, FL 33620, United States | |
kaust.person | Cairns, Amy | |
kaust.person | Belmabkhout, Youssef | |
kaust.person | Luebke, Ryan | |
kaust.person | Eddaoudi, Mohamed | |
kaust.person | Al Kordi, Mohamed | |
dc.relation.issupplementedby | DOI:10.5517/ccxptt6 | |
dc.relation.issupplementedby | DOI:10.5517/ccxpts5 | |
dc.relation.issupplementedby | DOI:10.5517/ccxptv7 | |
display.relations | <b> Is Supplemented By:</b> <br/> <ul><li><i>[Dataset]</i> <br/> Eubank, J. F., Mouttaki, H., Cairns, A. J., Belmabkhout, Y., Wojtas, L., Luebke, R., … Eddaoudi, M. (2012). CCDC 855129: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccxptt6. DOI: <a href="https://doi.org/10.5517/ccxptt6">10.5517/ccxptt6</a> HANDLE: <a href="http://hdl.handle.net/10754/624665">10754/624665</a></li><li><i>[Dataset]</i> <br/> Eubank, J. F., Mouttaki, H., Cairns, A. J., Belmabkhout, Y., Wojtas, L., Luebke, R., … Eddaoudi, M. (2012). CCDC 855128: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccxpts5. DOI: <a href="https://doi.org/10.5517/ccxpts5">10.5517/ccxpts5</a> HANDLE: <a href="http://hdl.handle.net/10754/624664">10754/624664</a></li><li><i>[Dataset]</i> <br/> Eubank, J. F., Mouttaki, H., Cairns, A. J., Belmabkhout, Y., Wojtas, L., Luebke, R., … Eddaoudi, M. (2012). CCDC 855130: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccxptv7. DOI: <a href="https://doi.org/10.5517/ccxptv7">10.5517/ccxptv7</a> HANDLE: <a href="http://hdl.handle.net/10754/624666">10754/624666</a></li></ul> |
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Advanced Membranes and Porous Materials Research Center
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