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    Suzuki-Miyaura cross-coupling coupling reactions with low catalyst loading: A green and sustainable protocol in pure water

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    Type
    Article
    Authors
    Fihri, Aziz
    Luart, Denis
    Len, Christophe
    Solhy, Abderrahim
    Chevrin, Carole
    Polshettiwar, Vivek cc
    KAUST Department
    KAUST Catalysis Center (KCC)
    Physical Science and Engineering (PSE) Division
    Date
    2011
    Permanent link to this record
    http://hdl.handle.net/10754/561649
    
    Metadata
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    Abstract
    The Suzuki-Miyaura coupling reaction represents one of the most important synthetic transformations developed in the 20th century. However, the use of toxic organic solvents remains a scientific challenge and an aspect of economical and ecological relevance, and benign water as a reaction medium was found to be highly effective to overcome some of these issues. In the present manuscript, we described Suzuki-Miyaura coupling reactions in neat water, without using any phase transfer reagent. Notably, this protocol also works with ultra-low loading of catalyst with high turnover numbers and also able to couple challenging substrates like aryl chlorides. © 2011 The Royal Society of Chemistry.
    Sponsors
    The authors acknowledge Ayoub Hassine for experimental work during his Master's training and the Region Picardie for their financial support.
    Publisher
    Royal Society of Chemistry (RSC)
    Journal
    Dalton Transactions
    DOI
    10.1039/c0dt01637c
    PubMed ID
    21340087
    ae974a485f413a2113503eed53cd6c53
    10.1039/c0dt01637c
    Scopus Count
    Collections
    Articles; Physical Science and Engineering (PSE) Division; KAUST Catalysis Center (KCC)

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