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    Guanidine-catalyzed enantioselective desymmetrization of meso-aziridines

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    Type
    Article
    Authors
    Zhang, Yan
    Kee, Choonwee
    Lee, Richmond
    Fu, Xiao
    Soh, J. Y T
    Loh, E. M F
    Huang, Kuo-Wei cc
    Tan, Choonhong
    KAUST Department
    Biological and Environmental Sciences and Engineering (BESE) Division
    Chemical Science Program
    Homogeneous Catalysis Laboratory (HCL)
    KAUST Catalysis Center (KCC)
    Physical Science and Engineering (PSE) Division
    Date
    2011
    Permanent link to this record
    http://hdl.handle.net/10754/561648
    
    Metadata
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    Abstract
    An amino-indanol derived chiral guanidine was developed as an efficient Brønsted base catalyst for the desymmetrization of meso-aziridines with both thiols and carbamodithioic acids as nucleophiles, which provided 1,2-difunctionalized ring-opened products in high yields and enantioselectivities. © The Royal Society of Chemistry.
    Citation
    Zhang, Y., Kee, C. W., Lee, R., Fu, X., Soh, J. Y.-T., Loh, E. M. F., … Tan, C.-H. (2011). Guanidine-catalyzed enantioselective desymmetrization of meso-aziridines. Chemical Communications, 47(13), 3897. doi:10.1039/c0cc05840h
    Publisher
    Royal Society of Chemistry (RSC)
    Journal
    Chemical Communications
    DOI
    10.1039/c0cc05840h
    PubMed ID
    21336394
    Relations
    Is Supplemented By:
    • [Dataset]
      Zhang, Y., Kee, C. W., Lee, R., Fu, X., Soh, J. Y.-T., Loh, E. M. F., … Tan, C.-H. (2011). CCDC 806368: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccw22ww. DOI: 10.5517/ccw22ww HANDLE: 10754/624627
    • [Dataset]
      Zhang, Y., Kee, C. W., Lee, R., Fu, X., Soh, J. Y.-T., Loh, E. M. F., … Tan, C.-H. (2011). CCDC 806369: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/ccw22xx. DOI: 10.5517/ccw22xx HANDLE: 10754/624628
    ae974a485f413a2113503eed53cd6c53
    10.1039/c0cc05840h
    Scopus Count
    Collections
    Articles; Biological and Environmental Sciences and Engineering (BESE) Division; Physical Science and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)

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