From metal-organic squares to porous zeolite-like supramolecular assemblies
KAUST DepartmentAdvanced Membranes and Porous Materials Research Center
Biological and Environmental Sciences and Engineering (BESE) Division
Physical Sciences and Engineering (PSE) Division
Chemical Science Program
Functional Materials Design, Discovery and Development (FMD3)
Permanent link to this recordhttp://hdl.handle.net/10754/561591
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AbstractWe report the synthesis, structure, and characterization of two novel porous zeolite-like supramolecular assemblies, ZSA-1 and ZSA-2, having zeolite gis and rho topologies, respectively. The two compounds were assembled from functional metal-organic squares (MOSs) via directional hydrogen-bonding interactions and exhibited permanent microporosity and thermal stability up to 300 °C. © 2010 American Chemical Society.
SponsorsWe gratefully acknowledge the financial support of the Natural Science Foundation of China (Grants 20701015, 20788101, and 21071059).
PublisherAmerican Chemical Society (ACS)